Structural relaxation and optical properties in transparent nanocrystalline β-quartz glass-ceramic

We studied structural relaxation in a nanocrystalline beta-quartz solid solution (s.s.) glass-ceramic through density measurement, and the effect of structural relaxation on its optical properties. The density of the glass-ceramic changed as structural relaxation proceeded in the glass phase. It was found that the glass-ceramic whose glass phase has a high fictive temperature shows a high optical transmittance because of less optical scattering. We also demonstrated that the refractive index difference between the crystal and glass phases call be calculated from the scattering coefficients of the specimens with different fictive temperatures. The calculated refractive index of the crystalline phase was in fair agreement with the indices of a high-quartz crystal. (c) 2006 Elsevier B.V. All rights reserved.