Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO2 Surfaces

被引：281

作者：

Pang, Chi Lun ^{[1
,2
]}

Lindsay, Robert ^{[3
]}

Thornton, Geoff ^{[1
,2
]}

机构：

[1] UCL, London Ctr Nanotechnol, London WC1H 0AJ, England

[2] UCL, Dept Chem, London WC1H 0AJ, England

[3] Univ Manchester, Ctr Corros & Protect, Sch Mat, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL REVIEWS | 2013年 / 113卷 / 06期

基金：

欧洲研究理事会;

关键词：

SCANNING-TUNNELING-MICROSCOPY; ENERGY-ELECTRON-DIFFRACTION; TIO2(110)-(1 X-1) SURFACE; TRANSITION-METAL OVERLAYERS; DENSITY-FUNCTIONAL THEORY; RAY PHOTOELECTRON-SPECTROSCOPY; FORMIC-ACID ADSORPTION; LOCAL BARRIER HEIGHT; BI-ISONICOTINIC ACID; ULTRATHIN CU FILMS;

D O I：

10.1021/cr300409r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

TiO2 is exploited in a number of applications, including solar power, catalysis, gas sensing, and corrosion protection, where surface properties are central to operation. This commercial importance drives cutting-edge research into this material; activity extends from development of novel titania-based structures exhibiting enhanced surface functionality to fundamental work aiming to gain mechanistic insight into surface processes. TiO2 is exploited in a number of applications, including solar power, catalysis, gas sensing, and corrosion protection, where surface properties are central to operation. This commercial importance drives cutting-edge research into this material; activity extends from development of novel titania-based structures exhibiting enhanced surface functionality to fundamental work aiming to gain mechanistic insight into surface processes.

引用

页码：3887 / 3948

页数：62

共 550 条

[1] Ultra-thin Si overlayers on the TiO2 (110)-(1x2) surface:: Growth mode and electronic properties [J].

Abad, J. ;

Rogero, C. ;

Mendez, J. ;

Lopez, M. F. ;

Martin-Gago, J. A. ;

Roman, E. .

SURFACE SCIENCE, 2006, 600 (13) :2696-2704

[2] Dissociative adsorption of NO on TiO2(110) argon ion bombarded surfaces [J].

Abad, J ;

Böhme, O ;

Román, E .

SURFACE SCIENCE, 2004, 549 (02) :134-142

[3] Dissociative adsorption of NO on TiO2(110)-(1 x 2) surface:: Ti2O3 rows as actives sites for the adsorption [J].

Abad, Jose ;

Bohme, Oliver ;

Roman, Elisa .

LANGMUIR, 2007, 23 (14) :7583-7586

[4] CO2 Adsorption, Diffusion, and Electron-Induced Chemistry on Rutile TiO2(110): A Low-Temperature Scanning Tunneling Microscopy Study [J].

Acharya, D. P. ;

Camillone, N., III ;

Sutter, P. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (24) :12095-12105

[5] A theoretical study of HCO2H adsorption on TiO2(110) [J].

Ahdjoudj, J ;

Minot, C .

CATALYSIS LETTERS, 1997, 46 (1-2) :83-91

[6] Oxygen vacancy promoting catalytic dehydration of formic acid on TiO2(110) by in situ scanning tunneling microscopic observation [J].

Aizawa, M ;

Morikawa, Y ;

Namai, Y ;

Morikawa, H ;

Iwasawa, Y .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (40) :18831-18838

[7] Sintering, oxidation, and chemical properties of size-selected nickel clusters on TiO2(110) [J].

Aizawa, M ;

Lee, S ;

Anderson, SL .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (10) :5001-5011

[8] Giant room temperature ferromagnetism in rutile TiO2 implanted by Co [J].

Aktas, B ;

Yildiz, F ;

Rameev, B ;

Khaibullin, R ;

Tagirov, L ;

Özdemir, M .

SECOND SEEHEIM CONFERENCE ON MAGNETISM, PROCEEDINGS, 2004, :3319-3323

[9] First-principles study of the TiO2(110) surface reduction upon Na adsorption -: art. no. 035402 [J].

Albaret, T ;

Finocchi, F ;

Noguera, C ;

De Vita, A .

PHYSICAL REVIEW B, 2002, 65 (03) :1-12

[10] Adsorption bond length for H2O on TiO2(110):: A key parameter for theoretical understanding -: art. no. 226104 [J].

Allegretti, F ;

O'Brien, S ;

Polcik, M ;

Sayago, DI ;

Woodruff, DP .

PHYSICAL REVIEW LETTERS, 2005, 95 (22)

← 1 2 3 4 5 6 7 8 9 10 →