Self-assembled nanofiltration membrane containing antimicrobial organosilica prepared by sol-gel process

被引:7
作者
Singh, Ajay K. [1 ]
Thakur, Amit K. [1 ]
Shahi, Vinod K. [1 ]
机构
[1] Cent Salt & Marine Chem Res Inst, Electromembrane Proc Div, CSIR, Bhavnagar 364002, Gujarat, India
关键词
Anti-biofouling; Bis(4 '-aminopropyl diethoxysilylphenyl); 1,3,4-oxadiazole; Polyvinyl alcohol; Nanofiltration; NANOPARTICLES; PERFORMANCE; SEPARATION; SIZE;
D O I
10.1016/j.desal.2012.10.011
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new silica monomer precursor, bis(4'-aminopropyldiethoxysilylphenyl) 1,3,4-oxadiazole (APDSPO), was synthesized by Barbiar-Grignard reaction. Nanofiltration membranes containing APDSPO (biocide active) and polyvinyl alcohol (PVA), were prepared by acid catalyzed sol-gel followed by formal cross-linking. These membranes were designed with good stabilities (hydraulic, mechanical and chemical), separation performance, and low surface roughness. These membranes showed microbial growth inhibiting properties and thus anti-biofilm/fouling nature. About 35.2 L m(-2) h(-1) flux and 54.5% salt rejection for feed NaCl solution (1 g/L) at 0.62 MPa applied pressure, indicate the suitability of membrane (PO-6) for water purification. Membrane performance data also ruled out anti-biofouling nature of PO-6 membrane. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:275 / 283
页数:9
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