Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks

被引：149

作者：

Kang, Narae ^{[1
,2
]}

Park, Ji Hoon ^{[1
,2
]}

Ko, Kyoung Chul ^{[1
,2
]}

Chun, Jiseul ^{[1
,2
]}

Kim, Eunchul ^{[1
,2
]}

Shin, Hee-Won ^{[1
,2
]}

Lee, Sang Moon ^{[3
]}

Kim, Hae Jin ^{[3
]}

Ahn, Tae Kyu ^{[1
,2
]}

Lee, Jin Yong ^{[1
,2
]}

Son, Seung Uk ^{[1
,2
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea

[3] Korea Basic Sci Inst, Taejon 350333, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 24期

关键词：

benzodifuran; cross-coupling; microporous materials; photocatalyst; tandem synthesis; HIGH-SURFACE-AREA; CONJUGATED POLYMERS; COPPER COMPLEXES; ANODE MATERIALS; CATALYSIS; AMINES; IMIDAZOLIUM; FRAMEWORKS; STABILITY; OXIDATION;

D O I：

10.1002/anie.201300655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5-triethynylbenzene and 2,5-diiodo-1,4-hydroquinone and intramolecular cyclization. The resultant benzodifuran-containing MON showed promising photocatalytic activities in the oxidative conversion of primary amines into imines. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6228 / 6232

页数：5

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