Diagnostics of ethanol conversion products by IR absorption spectroscopy

被引：6

作者：

Arkhipenko, V. I. ^{[1
]}

Zgirouski, S. M. ^{[1
]}

Karoza, A. G. ^{[1
]}

Kirillov, A. A. ^{[1
]}

Simonchik, L. V. ^{[1
]}

机构：

[1] Natl Acad Sci Belarus, BI Stepanov Inst Phys, 68 Nezavisimost Ave, Minsk 220072, BELARUS

来源：

JOURNAL OF APPLIED SPECTROSCOPY | 2013年 / 80卷 / 01期

关键词：

nonequilibrium plasma; conversion; Fourier spectrometer; infrared absorption spectroscopy; molecular vibrational-rotational bands; PD(111);

D O I：

10.1007/s10812-013-9727-2

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Infrared absorption spectroscopy is used to determine the molar fractions of absorbing components among ethanol conversion products in nonequilibrium atmospheric-pressure glow discharges. It is shown that, when the conservation of the number of atoms at the inlet and outlet of the plasma chemical reactor is taken into account, this also makes it possible to determine the molar fractions of the IR inactive molecules H-2, N-2, and O-2. The concentration of hydrogen in the conversion products was also monitored using a device based on the passage of hydrogen through a palladium membrane.

引用

页码：99 / 103

页数：5

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