New inorganic ligand μ3-[SbO(H2O)2]3- in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se)

被引：0

作者：

Pronin, A. S. ^{[1
]}

Mironov, Y., V ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Prosp Akad Lavrentieva, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

rhenium; chalcogen; antimony; cyanide; crystal structure; tetrahedral cluster complexes; CRYSTAL-STRUCTURES; CORE; COORDINATION;

D O I：

10.1007/s11172-022-3644-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed-ligand cluster complexes of the composition K-5[{Re4S3[SbO(H2O)(2)]}-(CN)(12)]center dot 8H(2)O (1) and K-5[{Re4Se3[SbO(H2O)(2)]}(CN)(12)] center dot 3H(2)O (2) bearing the new inorganic ligand mu(3)-[SbO(H2O)(2)](3-) were synthesized by the high-temperature reactions of ReI3 with Sb, S, or Se and KCN followed by the recrystallization of the soluble products from water. The structures of the new compounds were studied by X-ray diffraction analysis. Using mass spectrometry data, it was found that the mu(3)-[SbO(H2O)(2)](3-) ligand is deprotonated stibine oxide, which is additionally coordinated by two water molecules.

引用

页码：2179 / 2186

页数：8

共 35 条

[1]

[Anonymous], 2017, Bruker Apex3 Software Suite: Apex3, SADABS-2016/2 and SAINT, version 2018.7-2

[2]

[Anonymous], CRYSTAL IMPACT GBR

[3]

Balicheva TG., 1971, J STRUCT CHEM, V12, P384, DOI [10.1007/BF00744622, DOI 10.1007/BF00744622]

[4] Advances in the Engineering of Near Infrared Emitting Liquid Crystals and Copolymers, Extended Porous Frameworks, Theranostic Tools and Molecular Junctions Using Tailored Re6 Cluster Building Blocks [J].

Cordier, Stephane ;

Molard, Yann ;

Brylev, Konstantin A. ;

Mironov, Yuri V. ;

Grasset, Fabien ;

Fabre, Bruno ;

Naumov, Nikolay G. .

JOURNAL OF CLUSTER SCIENCE, 2015, 26 (01) :53-81

[5] Water-soluble Re6-clusters with aromatic phosphine ligands - from synthesis to potential biomedical applications [J].

Ivanov, Anton A. ;

Konovalov, Dmitry L. ;

Pozmogova, Tatiana N. ;

Solovieva, Anastasiya O. ;

Melnikov, Anatoly R. ;

Brylev, Konstantin A. ;

Kuratieva, Natalia, V ;

Yanshole, Vadim V. ;

Kirakci, Kaplan ;

Lang, Kamil ;

Cheltygmasheva, Svettana N. ;

Kitamura, Noboru ;

Shestopalova, Lidiya, V ;

Mironove, Yuri, V ;

Shestopalov, Michael A. .

INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (04) :882-892

[6] Temperature dependent emission of hexarhenium(III) clusters [Re6(μ3-S)8X6]4- (X = Cl-, Br-, and I-):: Analysis by four excited triplet-state sublevels [J].

Kitamura, N ;

Ueda, Y ;

Ishizaka, S ;

Yamada, K ;

Aniya, M ;

Sasaki, Y .

INORGANIC CHEMISTRY, 2005, 44 (18) :6308-6313

[7] Synthesis and luminescence properties of apically homoleptic octahedral rhenium clusters with pyrazole and 3,5-dimethylpyrazole [J].

Konovalov, Dmitriy I. ;

Ivanov, Anton A. ;

Vorotnikov, Yuri A. ;

Brylev, Konstantin A. ;

Eltsov, Ilia V. ;

Kuratieva, Natalia V. ;

Kitamura, Noboru ;

Mironov, Yuri V. ;

Shestopalov, Michael A. .

INORGANICA CHIMICA ACTA, 2019, 498

[8] Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole [J].

Konovalov, Dmitry, I ;

Ivanov, Anton A. ;

Vorotnikov, Yuri A. ;

Kuratieva, Natalia, V ;

Eltsov, Ilia, V ;

Kovalenko, Konstantin A. ;

Shestopalov, Michael A. .

INORGANIC CHEMISTRY, 2021, 60 (19) :14687-14696

[9] Comprehensive study of hexarhenium cluster complex Na4[{Re6Te8}( CN) 6]-In terms of a new promising luminescent and X-ray contrast agent [J].

Krasilnikova, Anna A. ;

Solovieva, Anastasiya O. ;

Ivanov, Anton A. ;

Trifonova, Kristina E. ;

Pozmogova, Tatiana N. ;

Tsygankova, Alphiya R. ;

Smolentsev, Anton I. ;

Kretov, Evgeniy I. ;

Sergeevichev, David S. ;

Shestopalov, Michael A. ;

Mironov, Yuri V. ;

Shestopalov, Alexander M. ;

Poveshchenko, Alexander F. ;

Shestopalova, Lidiya V. .

NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE, 2017, 13 (02) :755-763

[10] Cellular internalization and morphological analysis after intravenous injection of a highly hydrophilic octahedral rhenium cluster complex - a new promising X-ray contrast agent [J].

Krasilnikova, Anna A. ;

Solovieva, Anastasiya O. ;

Trifonova, Kristina E. ;

Brylev, Konstantin A. ;

Ivanov, Anton A. ;

Kim, Sung-Jin ;

Shestopalov, Michael A. ;

Fufaeva, Maria S. ;

Shestopalov, Alexander M. ;

Mironov, Yuri V. ;

Poveshchenko, Alexander F. ;

Shestopalova, Lidia V. .

CONTRAST MEDIA & MOLECULAR IMAGING, 2016, 11 (06) :459-466

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