Benzofuran-fused Phosphole: Synthesis, Electronic, and Electroluminescence Properties

被引：89

作者：

Chen, Hui ^{[1
]}

Delaunay, Wylliam ^{[2
]}

Li, Jing ^{[1
]}

Wang, Zuoyong ^{[1
]}

Bouit, Pierre-Antoine ^{[2
]}

Tondelier, Denis ^{[3
]}

Geffroy, Bernard ^{[4
]}

Mathey, Francois ^{[1
,5
]}

Duan, Zheng ^{[1
]}

Reau, Regis ^{[2
]}

Hissler, Muriel ^{[2
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Int Phosphorus Lab, Zhengzhou 450001, Peoples R China

[2] Univ Rennes 1, CNRS, Inst Sci Chim Rennes, F-35042 Rennes, France

[3] Ecole Polytech, CNRS, Lab Phys Interfaces & Couches Minces, UMR 7647, F-91128 Palaiseau, France

[4] CEA Saclay, Lab Chim Surfaces & Interfaces, IRAMIS, SPCSI, F-91191 Gif Sur Yvette, France

[5] Nanyang Technol Univ, CBC SPMS, Singapore 637371, Singapore

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 02期

关键词：

FIELD-EFFECT TRANSISTORS; PI-CONJUGATED SYSTEMS; GAP; MOLECULES; DESIGN; FURAN;

D O I：

10.1021/ol303260d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic route to novel benzofuran-fused phosphole derivatives 3-5 is described. These compounds showed optical and electrochemical properties that differ from their benzothiophene analog. Preliminary results show that 4 can be used as an emitter in OLEDs, illustrating the potential of these new compounds for opto-electronic applications.

引用

页码：330 / 333

页数：4

共 39 条

[1] Effects of aromatic spacers on the properties of organic field effect transistors based on π-extended tetrathiafulvalene derivatives [J].

Aleveque, Olivier ;

Frere, Pierre ;

Leriche, Philippe ;

Breton, Tony ;

Cravino, Antonio ;

Roncali, Jean .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (22) :3648-3651

[2] Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].

Allard, Sybille ;

Forster, Michael ;

Souharce, Benjamin ;

Thiem, Heiko ;

Scherf, Ullrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098

[3] Organophosphorus π-conjugated materials [J].

Baumgartner, Thomas ;

Reau, Regis .

CHEMICAL REVIEWS, 2006, 106 (11) :4681-4727

[4] Dibenzophosphapentaphenes: Exploiting P Chemistry for Gap Fine-Tuning and Coordination-Driven Assembly of Planar Polycyclic Aromatic Hydrocarbons [J].

Bouit, Pierre-Antoine ;

Escande, Aude ;

Szucs, Rozsa ;

Szieberth, Denes ;

Lescop, Christophe ;

Nyulaszi, Laszlo ;

Hissler, Muriel ;

Reau, Regis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (15) :6524-6527

[5] α-Oligofurans: Molecules without a Twist [J].

Bunz, Uwe H. F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) :5037-5040

[6] 2,2′-Biphospholes: Building Blocks for Tuning the HOMO-LUMO Gap of π-Systems Using Covalent Bonding and Metal Coordination [J].

Chen, Hui ;

Delaunay, Wylliam ;

Yu, Liujian ;

Joly, Damien ;

Wang, Zuoyong ;

Li, Jin ;

Wang, Zisu ;

Lescop, Christophe ;

Tondelier, Denis ;

Geffroy, Bernard ;

Duan, Zheng ;

Hissler, Muriel ;

Mathey, Francois ;

Reau, Regis .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (01) :214-217

[7] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[8] To what extent can aromaticity be defined uniquely? [J].

Cyrañski, MK ;

Krygowski, TM ;

Katritzky, AR ;

Schleyer, PV .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (04) :1333-1338

[9] TOWARD POLYPHOSPHOLES - SYNTHESIS AND STRUCTURE OF AN ALPHA-LINKED QUATERPHOSPHOLE [J].

DESCHAMPS, E ;

RICARD, L ;

MATHEY, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (11) :1158-1161

[10]

Deschamps E., 1991, Heteroat. Chem, V2, P377

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