Platinum(II)-bis(9-methyladenine) complexes;: N1 → N6 migration of Pt(II) vs deamination of coordinated methyladenine

被引：14

作者：

Klika, KD ^{[1
]}

Arpalahti, J ^{[1
]}

机构：

[1] Univ Turku, Dept Chem, FIN-20014 Turku, Finland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 06期

关键词：

D O I：

10.1039/b315987f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N-1) complex of cis-Pt-II(NH3)(2) in basic solution, whereafter deamination of the 9-methyladenine still coordinated at N-1 competes with a second migration step.

引用

页码：666 / 667

页数：2

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