Synthesis of UiO-66-NH2 derived heterogeneous copper (II) catalyst and study of its application in the selective aerobic oxidation of alcohols

被引：113

作者：

Hou, Junying ^{[1
]}

Luan, Yi ^{[1
]}

Tang, Jia ^{[1
]}

Wensley, Allison M. ^{[1
]}

Yang, Mu ^{[1
]}

Lu, Yunfeng ^{[2
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Key Lab Funct Mat Mol & Struct Construct, Beijing 100083, Peoples R China

[2] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90034 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2015年 / 407卷

基金：

国家高技术研究发展计划(863计划);

关键词：

Metal-organic frameworks; Heterogeneous catalysis; Aerobic oxidation; Copper catalysis; METAL-ORGANIC FRAMEWORKS; MOLECULAR-OXYGEN; ACID; EPOXIDATION; COMPLEXES; ALDEHYDES;

D O I：

10.1016/j.molcata.2015.06.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The three-dimensional Zr-based metal-organic framework UiO-66-NH2 was functionalized with salicylaldehyde using a post-synthetic modification (PSM) strategy, and then three kinds of copper (II) salts were successfully immobilized onto the surface of the amino-functionalized Zr-MOF. The SEM and PXRD results showed that the morphology and structure of Zr-MOF were retained after multiple transformations. The obtained UiO-66-Sal-CuCl2 catalyst exhibited excellent activity for the selective aerobic oxidation of primary aromatic alcohols using molecular oxygen as the oxygen source. Furthermore, the UiO-66-Sal-CuCl2 catalyst showed a good cycle performance. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：53 / 59

页数：7

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