Ligand-regulated assemblies of three 1D to 3D Cu(II) coordination polymers: Structural diversities and magnetic properties

被引：5

作者：

Kang, Yi-Fan ^{[1
]}

Wang, Yun-Luo ^{[1
]}

Xu, Li ^{[1
]}

Zhang, Wen-Qian ^{[2
]}

Cuo, Lei-Lei ^{[2
]}

Ma, Yang-Min ^{[1
]}

机构：

[1] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Key Lab Auxiliary Chem & Technol Chem Ind, Minist Educ, Xian 710021, Peoples R China

[2] Xinyang Agr & Forestry Univ, Coll Biol & Pharmaceut Engn, Xinyang 464000, Henan, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2020年 / 291卷

基金：

中国博士后科学基金;

关键词：

Cu(II) coordination polymers; Nicotinate N-Oxide; Isonicotinate N-Oxide; Structural diversity; Magnetic property; CLUSTER-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; N-OXIDE; ACID; SORPTION; CONFIGURATION; LUMINESCENT; RESOLUTION; SERIES; MN;

D O I：

10.1016/j.jssc.2020.121620

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three structurally diverse Cu(II) coordination polymers (CPs) from one-dimension (1D) to three-dimension (3D) upon nicotinate N-oxide (NNO) and isonicotinate N-oxide (INO) ligands have been synthesized solvothermally. CP 1 [Cu-3(NNO)(4)(OH)(2)(H2O)(2)](n) based on NNO ligand displays a 1D wavy double-chain. CP2[Cu(INO)(OH)](n) based on INO ligand possesses a 2D wavy double-sheet. CP3[Cu(INO)(CH3O)](n) based on INO ligand exhibits a 3D framework with 1D wavy channels. Structural comparisons indicate that the position of functional group of ligand, the coordination modes of ligand, the solvent system determine these diversified CPs. And Moreover, the structural diversity of CPs 1-3 further result in their different magnetic behaviors.

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页数：7

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