Lewis Acid-Base Adducts of 1-Mesityl- and 1-Chloro-2,3,4,5-tetraphenylborole

被引：35

作者：

Braunschweig, Holger ^{[1
]}

Chiu, Ching-Wen ^{[2
]}

Gamon, Daniela ^{[1
]}

Gruss, Katrin ^{[1
]}

Hoerl, Christian ^{[1
]}

Kupfer, Thomas ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Wahler, Johannes ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[2] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 09期

关键词：

Lewis acids; Lewis bases; Boroles; Conjugation; Antiaromaticity; REDUCTION CHEMISTRY; PENTAARYLBOROLES; ANTIAROMATICITY;

D O I：

10.1002/ejic.201201383

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron-deficient borole compounds exhibit a pronounced Lewis acidity that is enhanced due to their antiaromatic character so that even weak donors datively coordinate to form Lewis acid-base adducts. This contribution presents the synthesis and structural characterization of Lewis acid-base adducts formed by the reaction of 1-mesityl-2,3,4,5-tetraphen-ylborole and 4-picoline as well as 1-chloro-2,3,4,5-tetraphenylborole with various donors. The new compounds are characterized by means of multinuclear NMR spectroscopy and single-crystal X-ray diffraction techniques and compared to related systems.

引用

页码：1525 / 1530

页数：6

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