Binuclear complexes containing an iron(I)-mercury(I) bond from oxidation of trans-[Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2)] with HgX2 (Ph(2)Ppy equals 2-(diphenylphosphino)pyridine, X=Cl, SCN)

被引：16

作者：

Kuang, SM

Xue, F

Duan, CY

Mak, TCW

Zhang, ZZ

机构：

[1] CHINESE UNIV HONG KONG,SHATIN 100083,HONG KONG

[2] NANKAI UNIV,ELEMENTOORGAN CHEM LAB,TIANJIN,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

oxidation elimination; heterobimetallics; iron carbonyl; mercury (I); phosphine; crystal structure;

D O I：

10.1016/S0022-328X(96)06891-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

trans-[Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2)] reacts with HgX2 (X = Cl, SCN) in dichloromethane at room temperature to give heterodinuclear complexes XFe(CO)(2)(mu-Ph(2)Ppy)(2)HgX (X = SCN, 1; X = Cl, 2) containing an iron(I)-mercury(I) bond. The Fe(I)-Hg(O) bond length as determined by X-ray analysis is 2.527(2)Angstrom for 1 and 2.529(1)Angstrom for 2.

引用

页码：15 / 21

页数：7

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