Binuclear complexes containing an iron(I)-mercury(I) bond from oxidation of trans-[Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2)] with HgX2 (Ph(2)Ppy equals 2-(diphenylphosphino)pyridine, X=Cl, SCN)

被引：16

作者：

Kuang, SM

Xue, F

Duan, CY

Mak, TCW

Zhang, ZZ

机构：

[1] CHINESE UNIV HONG KONG,SHATIN 100083,HONG KONG

[2] NANKAI UNIV,ELEMENTOORGAN CHEM LAB,TIANJIN,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

oxidation elimination; heterobimetallics; iron carbonyl; mercury (I); phosphine; crystal structure;

D O I：

10.1016/S0022-328X(96)06891-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

trans-[Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2)] reacts with HgX2 (X = Cl, SCN) in dichloromethane at room temperature to give heterodinuclear complexes XFe(CO)(2)(mu-Ph(2)Ppy)(2)HgX (X = SCN, 1; X = Cl, 2) containing an iron(I)-mercury(I) bond. The Fe(I)-Hg(O) bond length as determined by X-ray analysis is 2.527(2)Angstrom for 1 and 2.529(1)Angstrom for 2.

引用

页码：15 / 21

页数：7

共 50 条

[21] Reactivity of trans-(CO)3Fe(Ph2Ppym)2 toward metal reagents: synthesis and crystal structures of [HgCl(Ph2Ppym) (ae-Cl)]2, trans-[(Ph2Ppym)2Rh(CO)Cl] u 0.5CH2Cl2, [PdCl(ae-Ph2Ppym)]2* CH2Cl2, cis- [ (Ph2Ppym)2PdCl2] u 0.5CH2Cl2 and cis-[Fe(NCS)2- {Ph2P(O)pym}2] (Ph2Ppym = 2-(diphenylphosphino)pyrimidine)
Li, S.-L.
Zhang, Z.-Z.
Wu, B.-M.
Mak, T. C. W.
Inorganica Chimica Acta, 255 (02):
[22] STERIC EFFECTS OF THE 2-(DIPHENYLPHOSPHINO)PYRIDINE BRIDGING LIGAND IN THE SYNTHESIS OF BINUCLEAR RHPD COMPLEXES - CRYSTAL-STRUCTURES OF [(CN-TERT-BU)2CL2RH(MU-PH2PPY)PD(MU-CL)]2 AND [(C8H12)RH(MU-CL)(MU-PH2PPY)PDCL2]
ARENA, CG
ROTONDO, E
FARAONE, F
LANFRANCHI, M
TIRIPICCHIO, A
ORGANOMETALLICS, 1991, 10 (11) : 3877 - 3885
[23] Reactivity of trans-(CO)(3)Fe(Ph(2)Ppym)(2) toward metal reagents: Synthesis and crystal structures of [HgCl(Ph(2)Ppym)(mu-Cl)](2), trans-[(Ph(2)Ppym)(2)Rh(CO)Cl]center dot 0.5CH(2)Cl(2), [PdCl(mu-Ph(2)Ppym)](2)center dot CH2Cl2, cis-[(Ph(2)Ppym)(2)PdCl2]center dot 0.5CH(2)Cl(2) and cis-[Fe(NCS)(2){Ph2P(O)pym}(2)] (Ph(2)Ppym=2-(diphenylphosphino)pyrimidine)
Li, SL
Zhang, ZZ
Wu, BM
Mak, TCW
INORGANICA CHIMICA ACTA, 1997, 255 (02) : 239 - 248
[24] Synthesis and chemistry of diphenyl-2-pyridylphosphine complexes of palladium(0).: X-ray characterisation of Pd(Ph2Ppy)2-(η2-DMAD) and trans-Pd(Ph2Ppy)2(PhC=CH2)(CF3CO2)
Dervisi, A
Edwards, PG
Newman, PD
Tooze, RP
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04): : 523 - 528
[25] On the transferability of Ir-I bond enthalpies between [Ir(μ-StBu)(I)2(CO)2]2 and trans-[Ir(X)(I)2(CO)(PPh3)2] (X = F, Cl, Br, I) complexes
Veiros, LF
da Piedade, MEM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 662 (1-2) : 105 - 111
[26] STUDIES ON BINUCLEAR COMPLEXES - THE SYNTHESIS AND MOLECULAR-STRUCTURE OF PDMO(MU-PH2PPY)2(MU-CO)(CO)2.0.5CH2CL2
ZHANG, ZZ
WANG, HK
WANG, HG
WANG, RJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (03) : 357 - 367
[27] BHMO MOLECULAR ORBITAL STUDY ON MoPd（μ-Ph2Ppy）2（μ-CO）(CO)2Cl2 AND RELATED COMPOUNDS CONTAINING Mo-to-METAL BOND
Wang Xukun Zhang ZhengzhiInstitute of Elementoorganic Chemistry
结构化学, 1987, (01) : 1 - 6
[28] SYNTHESIS AND CRYSTAL-STRUCTURE OF PDMO (MU-PH(2)PPY)(2)(MU-CO) (CO)(2)I-2-CENTER-DOT-0.5CH2CL2
ZHANG, ZZ
XI, HP
WANG, HG
WANG, RJ
ACTA CHIMICA SINICA, 1993, 51 (11) : 1053 - 1058
[29] Reaction of 2-(diphenylphosphino)-pyridine and -thiazole organoiron(0) polydentate ligands with iron(III) salts -: X-ray structures of [η2-Ph2P(O)py]2Fe(μ-Cl)2FeCl2 and Fe(NCS)2[η2-Ph2P(O)taz]2 (taz=thiazole)
Kuang, SM
Zhang, ZZ
Xue, F
Mak, TCW
POLYHEDRON, 1999, 18 (26) : 3465 - 3468
[30] PREPARATION OF TRANS-[PT(OX)2X2]2- (X=CL, BR, I, SCN, OH) BY OXIDATIVE ADDITION TO [PT(OX)2]2- IN ORGANIC-SOLVENTS
RIMKUS, G
PREETZ, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 502 (07): : 73 - 82

← 1 2 3 4 5 →