Mix-design and characterization of alkali activated materials based on metakaolin and ladle slag

Recycling industrial waste to produce new materials is a driving path to promote a sustainable development. Alkali activation can be a very effective tool to reach this goal especially when the starting material can be carbon fly ash and blast furnace slag instead of calcined natural clays such as metakaolin. With the aim to further increase the type of waste to be used as precursor and to promote a new recycling route, alkali activated materials based on partial substitution of metakaolin with ladle slag, deriving from the refining process of steel produced by arc electric furnace technology, are reported. In particular, being ladle slag rich in Ca-containing crystalline phases, its effect on the consolidation process has been investigated by means of microstructure analysis carried out with XRD, SEM and MIP techniques. The results show that ladle slag are activated by alkaline solutions and participate in gels formation. Indeed, an optimization in terms of ladle slag content (60-80 wt.%) and the coexistence of different types of gels (3D aluminosilicate, C-S-H and Ca-rich aluminosilicate) have been envisaged. (c) 2012 Elsevier B.V. All rights reserved.