Effects of Ti substitution on structural and magnetic properties of Zn-Mn ferrospinels

被引:4
|
作者
Patil, R. P. [1 ]
Patil, N. M. [1 ]
Sasikala, R. [2 ]
Hankare, P. P. [1 ]
Delekar, S. D. [3 ]
机构
[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India
[3] Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem, Subcampus Osmanabad 413501, India
关键词
Magnetic materials; Nanostructures; Sol-gel chemistry; Infrared spectroscopy; X-ray diffraction;
D O I
10.1016/j.materresbull.2013.01.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocrystalline ZnMn1-xTixFeO4 (1.0 >= x >= 0) ferrites were prepared by sol-gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction patterns. The lattice parameter shows an increasing trend with the increase in Ti content. These ferrite samples existed as crystalline nanoparticles of about 30-40 nm size as observed from transmission electron microscopy (TEM) technique. EDAX analysis indicated that the concentration of different elements in different compositions is in close agreement with the starting concentrations. Infrared spectra showed two main absorption bands in the range 400-800 cm(-1) arising due to tetrahedral (A) and octahedral (B) stretching vibrations. The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution. (C) 2013 Published by Elsevier Ltd.
引用
收藏
页码:1791 / 1795
页数:5
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