Highly efficient catalytic dechlorination of organic chlorides with a silica-supported Pd nanoparticle catalyst

被引：5

作者：

Ukisu, Yuji ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, AIST Tsukuba W, Tsukuba, Ibaraki 3058569, Japan

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2012年 / 107卷 / 02期

关键词：

Halogenated organic compounds; Detoxification; Environmental catalyst; Hydrogen transfer reaction; NOBLE-METAL CATALYSTS; HYDROGEN-TRANSFER HYDRODECHLORINATION; LIQUID-PHASE HYDRODECHLORINATION; PALLADIUM CATALYSTS; ACTIVITY ENHANCEMENT; ALKALINE; 2-PROPANOL; HYDRODEHALOGENATION; HALIDES; DIOXINS;

D O I：

10.1007/s11144-012-0489-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A silica-supported Pd nanoparticle catalyst was prepared by refluxing a Pd(II) precursor in alkaline 2-propanol; it consisted of metallic Pd nanoparticles (ca. 2-8 nm) dispersed in the silica-gel pores. This catalyst exhibited much more efficient dechlorination of p-chloroanisole and 1,1-bis(4-chlorophenyl)-2,2-dichloroethylene (DDE) in an alkaline 2-propanol/methanol (99:1 v/v) solution than a conventional Pd/C catalyst.

引用

页码：277 / 284

页数：8

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