Recent Advances in the Nanocatalyst-Assisted NaBH4 Reduction of Nitroaromatics in Water

被引：222

作者：

Zhang, Kaiqiang ^{[1
,2
]}

Suh, Jun Min ^{[1
]}

Choi, Ji-Won ^{[2
]}

Jang, Ho Won ^{[1
]}

Shokouhimehr, Mohammadreza ^{[1
]}

Varma, Rajender S. ^{[3
,4
]}

机构：

[1] Seoul Natl Univ, Res Inst Adv Mat, Dept Mat Sci & Engn, Seoul 08826, South Korea

[2] Korea Inst Sci & Technol, Ctr Elect Mat, Seoul 136791, South Korea

[3] Palacky Univ, Fac Sci, Dept Phys Chem, Reg Ctr Adv Technol & Mat, Slechtitelu 27, Olomouc 78371, Czech Republic

[4] US EPA, Water Resources Recovery Branch, Water Syst Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

来源：

ACS OMEGA | 2019年 / 4卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

ENHANCED CATALYTIC-ACTIVITY; CORE-SHELL NANOPARTICLES; AROMATIC NITRO-COMPOUNDS; RECYCLABLE HETEROGENEOUS CATALYST; ONE-STEP SYNTHESIS; SILVER NANOPARTICLES; GOLD NANOPARTICLES; HIGHLY EFFICIENT; NANOCOMPOSITE CATALYSTS; PALLADIUM NANOPARTICLES;

D O I：

10.1021/acsomega.8b03051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In view of the increasing applications of nanocatalysis in chemical transformations, this article illustrates recent advances on the use of nanocatalysts for an important reduction reaction, the hydrogenation of nitroaromatics to significant aminoaromatics with aqueous NaBH4 solution; the utility of mono- and multimetal nanocatalysts with special emphasis on heterogeneous nanocatalysts is included. A progressive trend on the applicability of nanocatalysts is also incorporated with large-scale application and their sustainable recyclization and reuse utilizing supported and magnetic nanocatalysts; representative methods for the synthesis of such reusable nanocatalysts are featured.

引用

页码：483 / 495

页数：13

共 100 条

[1] Fe3O4@Carbon Microsphere Supported Ag-Au Bimetallic Nanocrystals with the Enhanced Catalytic Activity and Selectivity for the Reduction of Nitroaromatic Compounds [J].

An, Qiao ;

Yu, Meng ;

Zhang, Yuting ;

Ma, Wanfu ;

Guo, Jia ;

Wang, Changchun .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (42) :22432-22440

[2] Impact of Gold Nanoparticle Stabilizing Ligands on the Colloidal Catalytic Reduction of 4-Nitrophenol [J].

Ansar, Siyam M. ;

Kitchens, Christopher L. .

ACS CATALYSIS, 2016, 6 (08) :5553-5560

[3] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[4] Magnetic polyaniline-chitosan nanocomposite decorated with palladium nanoparticles for enhanced catalytic reduction of 4-nitrophenol [J].

Ayad, Mohamad M. ;

Amer, Wael A. ;

Kotp, Mohammed G. .

MOLECULAR CATALYSIS, 2017, 439 :72-80

[5] Synthesis of silver-anchored polyaniline-chitosan magnetic nanocomposite: a smart system for catalysis [J].

Ayad, Mohamad M. ;

Amer, Wael A. ;

Kotp, Mohammed G. ;

Minisy, Islam M. ;

Rehab, Ahmed F. ;

Kopecky, Dusan ;

Fitl, Premysl .

RSC ADVANCES, 2017, 7 (30) :18553-18560

[6] Magnetic Fe@g-C3N4: A Photoactive Catalyst for the Hydrogenation of Alkenes and Alkynes [J].

Baig, R. B. Nasir ;

Verma, Sanny ;

Varma, Rajender S. ;

Nadagouda, Mallikarjuna N. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (03) :1661-1664

[7] Organic synthesis via magnetic attraction: benign and sustainable protocols using magnetic nanoferrites [J].

Baig, R. B. Nasir ;

Varma, Rajender S. .

GREEN CHEMISTRY, 2013, 15 (02) :398-417

[8] Ultra small gold nanoparticles-graphitic carbon nitride composite: an efficient catalyst for ultrafast reduction of 4-nitrophenol and removal of organic dyes from water [J].

Bhowmik, Tanmay ;

Kundu, Manas Kumar ;

Barman, Sudip .

RSC ADVANCES, 2015, 5 (48) :38760-38773

[9] Selective hydrogenation for fine chemicals: Recent trends and new developments [J].

Blaser, HU ;

Malan, C ;

Pugin, B ;

Spindler, F ;

Steiner, H ;

Studer, M .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :103-151

[10] A branched-dumbbell Pt/NiFe nanostructure and its high catalytic reduction activity for nitro-aromatic compounds [J].

Chen, Hanxing ;

Zhou, Linyi ;

Wen, Ming ;

Wu, Qingsheng ;

Wang, Chenxiang .

MATERIALS RESEARCH BULLETIN, 2014, 60 :322-327

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