SYNTHESIS OF A NEW LAYERED Zn(II) COORDINATION POLYMER VIA DUAL-LIGAND STRATEGY: LUMINESCENCE SENSING FOR DETECTION OF Fe3+ ION

被引：0

作者：

Tang, Y. ^{[1
]}

Yao, X. ^{[2
]}

机构：

[1] Guangdong Univ Petrochem Technol, Anal & Testing Ctr, Maoming, Guangdong, Peoples R China

[2] Guangdong Univ Petrochem Technol, Sch Chem, Maoming, Guangdong, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2022年 / 63卷 / 11期

关键词：

Zn(II) compound; 2D layer; hydrothermal synthesis; luminescence; supramolecular framework; FRAMEWORK; SENSOR;

D O I：

10.1134/S002247662211004X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Zn(II) coordination polymer with the formula of [Zn(L)(4,4 '-Hbpt)](n) (1, H2L = 5-[(3-carboxy-4hydroxyphenyl)sulfanyl]-2-hydroxybenzoic acid, 4,4 '-Hbpt = 1H-3,5-bis(4-pyridyl)-1,2,4-triazole) has been successfully synthesized under hydrothermal conditions. Structural characterization revealed that compound 1 displays a 2D layered structure with 4-connected sql topology. Interlayer N-H?O hydrogen bonds finally directed these 2D layers into an interdigitated 3D supramolecular framework. Interestingly, compound 1 shows moderate sensing ability for the recognition of Fe3+ ion and the minimum limit of detection (LOD) for Fe3+ is 0.05 mM, indicating that such layered structure can be applied as a luminescence probe for the detection of Fe3+ ion.

引用

页码：1751 / 1757

页数：7

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