Extraction of magnesia from Egyptian serpentine ore via reaction with different acids .1. Reaction with sulfuric acid

被引:16
作者
Fouda, MFR
Amin, RE
Mohamed, M
机构
[1] Inorganic Chemistry Department, National Research Centre, Dokki, Cairo
关键词
D O I
10.1246/bcsj.69.1907
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present study is concerned with the effectiveness of use of local Egyptian serpentine ore for production of magnesium sulfate. An investigation of the ore composition was carried out by means of X-ray diffractometry and chemical analysis. The reaction of sulfuric acid with the ore was studied at different leach parameters under laboratory conditions for the uncalcined and calcined ore. The dissolution rate constants of magnesia were determined by the analysis of the experimental data The resultant activation energy of reaction between the acid and the studied ore was lower than the values reported previously. This result is discussed in terms of structural changes of serpentine during the calcination of ore which may affect its reactivity towards acids. The high yield of magnesia extraction from the ore emphasizes the possibility of exploitation of the ore in the preparation of sulfate salt with a lower price.
引用
收藏
页码:1907 / 1912
页数:6
相关论文
共 19 条
[1]  
AMIN RS, 1993, SILICATES IND, V1, P7
[2]   KINETICS OF SULFURIC-ACID LEACHING OF NICKEL AND MAGNESIUM FROM REDUCTION ROASTED SERPENTINE [J].
APOSTOLIDIS, CI ;
DISTIN, PA .
HYDROMETALLURGY, 1978, 3 (02) :181-196
[3]   REACTION-KINETICS PARAMETERS DESCRIBING DISPLACEMENT BY ACIDS OF STRUCTURAL METALLIC-IONS FROM CLAY-MINERALS [J].
AUBERT, WG ;
BERNARD, WJ ;
CONSTANT, WD .
CHEMICAL ENGINEERING COMMUNICATIONS, 1989, 78 :201-211
[4]  
Ball M.C., 1961, MINERAL MAG J M SOC, V32, P754, DOI 10.1180/minmag.1961.032.253.02
[5]  
BRINDLEY CW, 1964, CLAYS CLAY MINER, V12, P35
[6]  
BRINDLEY GW, 1957, AM MINERAL, V42, P461
[7]  
*ELBS ENGL BOOK SO, 1978, VOG TXB QUIN IN AN, P135
[8]  
FROST AA, 1961, KINETICS MECHANISM, P99
[9]  
Glasstone S, 1961, THEORY RATE PROCESSE
[10]   RECORD OF LEAD POLLUTION IN SEDIMENTS OF THE TOKYO BAY, JAPAN [J].
HIRAO, Y ;
MATSUMOTO, E ;
TODOROKI, H ;
IMAMURA, T ;
FUKUDA, E ;
KIMURA, K .
GEOCHEMICAL JOURNAL, 1983, 17 (01) :19-27