Synthesis and characterization of a shock-synthesized cubic B-C-N solid solution of composition BC2.5N

被引：105

作者：

Komatsu, T ^{[1
]}

Nomura, M ^{[1
]}

Kakudate, Y ^{[1
]}

Fujiwara, S ^{[1
]}

机构：

[1] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1996年 / 6卷 / 11期

关键词：

D O I：

10.1039/jm9960601799

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A cubic BC2.5N solid solution (c-BC2.5N) was synthesized in 18% yield by shock-compression of a hexagonal BC2.5N compound. c-BC2.5N was confirmed to have a diamond structure without a long range order of atomic arrangement. The material is a polycrystal composed of microcrystals of 5-20 nm in size. All constituent atoms are teterahedrally coordinated, giving C-C, C-B, C-N, and B-N bonds, and are homogeneously distributed on the lattice planes rather than showing a full short range order of atomic arrangement.

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页码：1799 / 1803

页数：5

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