Multi layer spin-coating deposition of poly(vinylidene fluoride) films for controlling thickness and piezoelectric response

被引:57
作者
Cardoso, V. F. [1 ]
Minas, G. [1 ]
Lanceros-Mendez, S. [2 ,3 ]
机构
[1] Univ Minho, Algoritmi Ctr, P-4800058 Guimaraes, Portugal
[2] Univ Minho, Dept Ctr Phys, P-4710057 Braga, Portugal
[3] INL Int Iberian Nanotechnol Lab, P-4715330 Braga, Portugal
关键词
Electroactive polymers; Transducers; Piezoelectric; Functionally graded materials; BETA-PHASE; PVDF FILMS; POLYMERS; TRANSFORMATION;
D O I
10.1016/j.sna.2012.12.019
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Poly(vinylidene fluoride), PVDF, films have been processed by spin-coating with controlled thickness by multilayer film deposition. Films with thickness ranging from 300 nm to 25 mu m, beta-phase content up to 80%, piezoelectric coefficient d(33) up to similar to-20 pC/N and an optical transmittance in the visible range higher than 70%, were obtained with a one to three layer deposition process. The influence of the annealing temperature in the different layers is discussed as well as the possibility of obtaining functionally graded electroactive polymers though controlling spin-coating deposition parameters and thermal annealing of the different layers. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:76 / 80
页数:5
相关论文
共 17 条
[1]   Poled polymers for sensors and photonic applications [J].
Bauer, S .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (10) :5531-5558
[2]   Micro and nanofilms of poly(vinylidene fluoride) with controlled thickness, morphology and electroactive crystalline phase for sensor and actuator applications [J].
Cardoso, V. F. ;
Minas, G. ;
Costa, C. M. ;
Tavares, C. J. ;
Lanceros-Mendez, S. .
SMART MATERIALS AND STRUCTURES, 2011, 20 (08)
[3]   Lab-on-a-Chip With β-Poly(Vinylidene Fluoride) Based Acoustic Microagitation [J].
Cardoso, V. F. ;
Catarino, S. O. ;
Nunes, J. Serrado ;
Rebouta, L. ;
Rocha, J. G. ;
Lanceros-Mendez, S. ;
Minas, G. .
IEEE TRANSACTIONS ON BIOMEDICAL ENGINEERING, 2010, 57 (05) :1184-1190
[4]   Influence of the Solvent Evaporation Rate on the Crystalline Phases of Solution-Cast Poly(Vinylidene Fluoride) Films [J].
Chinaglia, Dante Luis ;
Gregorio, Rinaldo, Jr. ;
Stefanelo, Josiani Cristina ;
Pisani Altafim, Ruy Alberto ;
Wirges, Werner ;
Wang, Feipeng ;
Gerhard, Reimund .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (02) :785-791
[5]   Functionally graded electroactive Poly(vinylidene fluoride) polymers [J].
Costa, C. M. ;
Gomes, J. ;
Nunes, J. Serrado ;
Sencadas, V. ;
Lanceros-Mendez, S. .
INTERNATIONAL JOURNAL OF MATERIALS & PRODUCT TECHNOLOGY, 2010, 39 (1-2) :178-185
[6]   A history of medical and biological imaging with polyvinylidene fluoride (PVDF) transducers [J].
Foster, FS ;
Harasiewicz, EA ;
Sherar, MD .
IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL, 2000, 47 (06) :1363-1371
[7]   Influence of the β-phase content and degree of crystallinity on the piezo- and ferroelectric properties of poly(vinylidene fluoride) [J].
Gomes, J. ;
Nunes, J. Serrado ;
Sencadas, V. ;
Lanceros-Mendez, S. .
SMART MATERIALS AND STRUCTURES, 2010, 19 (06)
[8]  
GREGORIO R, 1994, J POLYM SCI POL PHYS, V32, P859, DOI 10.1002/polb.1994.090320509
[9]   Nucleation of the Electroactive γ Phase and Enhancement of the Optical Transparency in Low Filler Content Poly(vinylidene)/Clay Nanocomposites [J].
Lopes, A. C. ;
Costa, C. M. ;
Tavares, C. J. ;
Neves, I. C. ;
Lanceros-Mendez, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (37) :18076-18082
[10]   FERROELECTRIC POLYMERS [J].
LOVINGER, AJ .
SCIENCE, 1983, 220 (4602) :1115-1121