Simple method for the fluorinated functionalization of graphene oxide

被引:45
作者
Pu, Linyu [1 ]
Ma, Yongjun [1 ]
Zhang, Wei [2 ]
Hu, Hailong [3 ]
Zhou, Yong [4 ,5 ]
Wang, Qionglin [2 ]
Pei, Chonghua [1 ]
机构
[1] Southwest Univ Sci & Technol, State Key Lab Cultivat Base Nonmetal Composite &, Mianyang 621010, Peoples R China
[2] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
[3] Southwest Univ Sci & Technol, Analyt & Testing Ctr, Mianyang 621010, Peoples R China
[4] Nanjing Univ, Sch Phys, ERERC, Nanjing 210093, Jiangsu, Peoples R China
[5] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
关键词
FLUORIDES;
D O I
10.1039/c2ra20585h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorinated graphene was reported and its outstanding properties and structure impressed everyone, but there was a lack of extensive preparation and application due to the use of expensive graphene and hazardous fluorinating agents. Now we have developed a simple, highly-effective, low-cost, and large-scale process for the preparation of monolayered FGO.
引用
收藏
页码:3881 / 3884
页数:4
相关论文
共 19 条
[1]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[2]   Synthesis and properties of monolayer graphene oxyfluoride [J].
Bruna, Matteo ;
Massessi, Barbara ;
Cassiago, Cristina ;
Battiato, Alfio ;
Vittone, Ettore ;
Speranza, Giorgio ;
Borini, Stefano .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (46) :18730-18737
[3]   Facile Synthesis of Wide-Bandgap Fluorinated Graphene Semiconductors [J].
Chang, Haixin ;
Cheng, Jinsheng ;
Liu, Xuqing ;
Gao, Junfeng ;
Li, Mingjian ;
Li, Jinghong ;
Tao, Xiaoming ;
Ding, Feng ;
Zheng, Zijian .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (32) :8896-8903
[4]   Reversible fluorination of graphene: Evidence of a two-dimensional wide bandgap semiconductor [J].
Cheng, S. -H. ;
Zou, K. ;
Okino, F. ;
Gutierrez, H. R. ;
Gupta, A. ;
Shen, N. ;
Eklund, P. C. ;
Sofo, J. O. ;
Zhu, J. .
PHYSICAL REVIEW B, 2010, 81 (20)
[5]   Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane [J].
Elias, D. C. ;
Nair, R. R. ;
Mohiuddin, T. M. G. ;
Morozov, S. V. ;
Blake, P. ;
Halsall, M. P. ;
Ferrari, A. C. ;
Boukhvalov, D. W. ;
Katsnelson, M. I. ;
Geim, A. K. ;
Novoselov, K. S. .
SCIENCE, 2009, 323 (5914) :610-613
[6]   SYNTHESIS OF AROMATIC FLUORIDES THROUGH DIAZOTIZATION IN ANHYDROUS HYDROGEN FLUORIDE [J].
FERM, RL ;
VANDERWERF, CA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (10) :4809-4810
[7]   Chemically modified graphene sheets by functionalization of highly exfoliated graphite [J].
Grayfer, Ekaterina D. ;
Nazarov, Albert S. ;
Makotchenko, Viktor G. ;
Kim, Sung-Jin ;
Fedorov, Vladimir E. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (10) :3410-3414
[8]   Unraveling Structural Models of Graphite Fluorides by Density Functional Theory Calculations [J].
Han, Sang Soo ;
Yu, Ted H. ;
Merinov, Boris V. ;
van Duin, Adri C. T. ;
Yazami, Rachid ;
Goddard, William A., III .
CHEMISTRY OF MATERIALS, 2010, 22 (06) :2142-2154
[9]   Fluorographene: A Wide Bandgap Semiconductor with Ultraviolet Luminescence [J].
Jeon, Ki-Joon ;
Lee, Zonghoon ;
Pollak, Elad ;
Moreschini, Luca ;
Bostwick, Aaron ;
Park, Cheol-Min ;
Mendelsberg, Rueben ;
Radmilovic, Velimir ;
Kostecki, Robert ;
Richardson, Thomas J. ;
Rotenberg, Eli .
ACS NANO, 2011, 5 (02) :1042-1046
[10]   Simultaneous Nitrogen Doping and Reduction of Graphene Oxide [J].
Li, Xiaolin ;
Wang, Hailiang ;
Robinson, Joshua T. ;
Sanchez, Hernan ;
Diankov, Georgi ;
Dai, Hongjie .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (43) :15939-15944