A new sensitive and selective fluorescence probe for detection of cyanide

被引:29
作者
Duan, Yi-Long [1 ]
Zheng, Yan-Song [1 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorescence probe; Cyanide anion; alpha-p-Trifluoroacetamidophenyl-4-alkoxycinnamonitrile; alpha-p-Aminophenyl-4-alkoxycinnamonitrile; Hydrogen sulfite anion; TURN-ON DETECTION; GOLD NANOPARTICLES; AGGREGATION; SENSOR; DISSOLUTION; BLOOD;
D O I
10.1016/j.talanta.2013.01.048
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A class of new fluorescence probe alpha-p-trifluoroacetamidophenyl-4-alkoxycinnamonitrile for detection of cyanide anion was synthesized by the trifluoroacetylation of the fluorophore alpha-p-aminophenyl-4-alkoxycinnamonitrile. It was found that the probe could selectively detect cyanide anions, even in the presence of hydrogen sulfite and dicarbonate anions which were reported to easily interfere with the detection. The concentration of the cyanide anions that could be detected was as low as 1.0 mu M. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:332 / 337
页数:6
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