Noncovalent Functionalization of Black Phosphorus

被引：206

作者：

Abellan, Gonzalo ^{[1
,2
]}

Lloret, Vicent ^{[1
,2
]}

Mundloch, Udo ^{[1
,2
]}

Marcia, Mario ^{[1
,2
]}

Neiss, Christian ^{[5
]}

Goerling, Andreas ^{[5
]}

Varela, Maria ^{[3
,4
]}

Hauke, Frank ^{[1
,2
]}

Hirsch, Andreas ^{[1
,2
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany

[2] Joint Inst Adv Mat & Proc ZMP, Dr Mack Str 81, D-90762 Furth, Germany

[3] Univ Complutense Madrid, Inst Pluridisciplinar, E-28040 Madrid, Spain

[4] Univ Complutense Madrid, Fac CC Fis, E-28040 Madrid, Spain

[5] Friedrich Alexander Univ Erlangen Nurnberg FAU, Lehrstuhl Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 47期

基金：

欧洲研究理事会;

关键词：

black phosphorus; charge transfer; functionalization; noncovalent interactions; stability; FIELD-EFFECT TRANSISTORS; PERYLENE BISIMIDES; TCNQ; EXFOLIATION; CHEMISTRY; GRAPHENE; PASSIVATION; ELECTRONICS; DIANION; SYSTEMS;

D O I：

10.1002/anie.201604784

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Black phosphorus (BP) was functionalized with organic moieties on the basis of liquid exfoliation. The treatment of BP with electron-withdrawing 7,7,8,8-tetra-cyano-p-quinodimethane (TCNQ) led to electron transfer from BP to the organic dopant. On the other hand, the noncovalent interaction of BP with a perylene diimide was mainly due to van der Waals interactions but also led to considerable stabilization of the BP flakes against oxygen degradation.

引用

页码：14557 / 14562

页数：6

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