Copper- and vanadium-catalyzed asymmetric oxidations

被引：115

作者：

Bolm, C ^{[1
]}

Schlingloff, G ^{[1
]}

Bienewald, F ^{[1
]}

机构：

[1] UNIV MARBURG, FACHBEREICH CHEM, D-35032 MARBURG, GERMANY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 117卷 / 1-3期

关键词：

Baeyer-Villiger oxidation; asymmetric catalysis; sulfide oxidation;

D O I：

10.1016/S1381-1169(96)00359-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two asymmetric metal-catalyzed oxidations are discussed. Chiral copper complexes catalyze enantiospecific Baeyer-Villiger oxidations giving optically active lactones in up to 95% ee. Vanadium complexes have been used in enantioselective sulfide oxidations with hydrogen peroxide.

引用

页码：347 / 350

页数：4

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