Mechanical properties and compatibility of sulfonated poly(ethylene terephthalate)/cyclic olefin copolymer/maleic anhydride-grafted polyethylene-octene elastomer

被引:8
作者
Chiu, Hsien-Tang [1 ]
Chuang, Chao-Yin [1 ]
机构
[1] Natl Taiwan Univ Sci & Technol, Grad Sch Polymer Engn, Taipei 106, Taiwan
关键词
compatibilizer; cyclic olefin copolymer; maleic anhydride-grafted polyethylene-octene elastomer; sulfonated poly(ethylene terephthalate);
D O I
10.1080/03602550802129478
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A compatibilizer was added to blends of sulfonated poly(ethylene terephthalate) (SPET) and cyclic olefin copolymer (COC) and the effects were studied. The compatibilizer was maleic anhydride-grafted polyethylene-octene elastomer (POE-g-MA). It was hoped that maleic anhydride (MA) would react with carbonyl groups in the SPET molecules, owing to POE and COC being olefinic polymers and therefore compatible with each other. The compatibilization effects of the 80SPET/20COC/15POE-g-MA composite were measured using a dynamic mechanical analyzer (DMA) and scanning electron microscopy (SEM). Mechanical properties and rheological behavior were also studied. The results showed that there are partial compatibilizations for SPET/POE-g-MA and SPET/COC cases. Because POE-g-MACOCSPET in viscosity, COC in SPET has particle size 1-3m and POE-g-MA has particle size 5-30m, both resulting in almost no difference in impact strength.
引用
收藏
页码:649 / 654
页数:6
相关论文
共 40 条
[1]   Super-toughness in compatibilized poly(butylene terephthalate)/poly(ethylene-octene) copolymer blends [J].
Aróstegui, A ;
Nazábal, J .
POLYMER ENGINEERING AND SCIENCE, 2003, 43 (10) :1691-1701
[2]   Toughened poly(butylene terephthalate) by blending with a metallocenic poly(ethylene-octene) copolymer [J].
Aróstegui, A ;
Gaztelumendi, M ;
Nazábal, J .
POLYMER, 2001, 42 (23) :9565-9574
[3]   Plastic damage mechanisms of polypropylene/polyamide 6/polyethelene octene elastomer blends under cyclic tension [J].
Bai, SL ;
Wang, M .
POLYMER, 2003, 44 (21) :6537-6547
[4]   MORPHOLOGICAL ORIGIN OF SUPER TOUGHNESS IN POLY(ETHYLENE-TEREPHTHALATE) POLYETHYLENE BLENDS [J].
CARTE, TL ;
MOET, A .
JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 48 (04) :611-624
[5]   Compatibilization of poly(ethylene terephthalate)/polypropylene blends with maleic anhydride grafted polyethylene-octene elastomer [J].
Chiu, HT ;
Hsiao, YK .
JOURNAL OF POLYMER RESEARCH, 2006, 13 (02) :153-160
[6]   Impact-modified poly(ethylene terephthalate)/polyethylene-octene elastomer blends [J].
Chiu, HT ;
Hsiao, YK .
JOURNAL OF POLYMER RESEARCH, 2005, 12 (05) :355-359
[7]   Mechanical and fracture characterization of 50:50 HDPE/PET blends presenting different phase morphologies [J].
Fasce, L ;
Seltzer, R ;
Frontini, P ;
Pita, VJR ;
Pacheco, EBAV ;
Dias, ML .
POLYMER ENGINEERING AND SCIENCE, 2005, 45 (03) :354-363
[8]   Polypropylene/polyamide 6/polyethylene-octene elastomer blends. Part 2: volume dilatation during plastic deformation under uniaxial tension [J].
G'Sell, C ;
Bai, SL ;
Hiver, JM .
POLYMER, 2004, 45 (17) :5785-5792
[9]   Supertoughness in poly sulfone/poly (ethylene-octene) blends [J].
Guerrica-Echevarría, G ;
Eguiazábal, JI ;
Nazábal, J .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2005, 290 (01) :38-44
[10]   Maleic anhydride polyethylene octene elastomer toughened polyarnide 6/polypropylene nanocomposites: Mechanical and morphological properties [J].
Hassan, Azman ;
Othman, Norhayani ;
Wahit, Mat Uzir ;
Wei, Lim Jian ;
Rahmat, Abdul Razak ;
Ishak, Zainal Ariffin Mohd .
MACROMOLECULAR SYMPOSIA, 2006, 239 :182-191