Porous metal-organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake

被引:45
作者
Gao, Wen-Yang [1 ]
Niu, Youhong [1 ]
Chen, Yao [1 ]
Wojtas, Lukasz [1 ]
Cai, Jianfeng [1 ]
Chen, Yu-Sheng [2 ]
Ma, Shengqian [1 ]
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA
来源
CRYSTENGCOMM | 2012年 / 14卷 / 19期
基金
美国国家科学基金会;
关键词
CARBON-DIOXIDE CAPTURE; C BOND-CLEAVAGE; HYDROGEN STORAGE; ADSORPTION; FUNCTIONALIZATION; SEPARATION; PLATFORM; CHLORIDE; BINDING; DESIGN;
D O I
10.1039/c2ce25484k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A two-fold interpenetrating microporous metal-organic framework, MMCF-1, has been constructed via the self-assembly of a custom-designed macrocyclic tetracarboxylate ligand and Cd(II), and it exhibits interesting selective uptake of CO2 over N-2.
引用
收藏
页码:6115 / 6117
页数:3
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