A solvent-switched in situ confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution

被引：61

作者：

Zhu, Qi-Long ^{[1
]}

Song, Fu-Zhan ^{[1
]}

Wang, Qiu-Ju ^{[1
]}

Tsumori, Nobuko ^{[3
]}

Himeda, Yuichiro ^{[4
]}

Autrey, Tom ^{[5
]}

Xu, Qiang ^{[1
,2
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Electrochem Energy, Ikeda, Osaka 5638577, Japan

[2] Kyoto Univ, Chem Energy Mat Open Innovat Lab ChEM OIL, AIST, Sakyo Ku, Kyoto 6068501, Japan

[3] Toyama Natl Coll Technol, 13 Hongo Machi, Toyama 9398630, Japan

[4] AIST, Res Inst Energy Frontier, Tsukuba Cent 5,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

[5] Pacific Northwest Natl Lab, 902 Battelle Blvd, Richland, WA 99352 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2018年 / 6卷 / 14期

关键词：

METAL-ORGANIC FRAMEWORKS; FORMIC-ACID DECOMPOSITION; ROOM-TEMPERATURE; AMBIENT CONDITIONS; PD NANOPARTICLES; HIGH-PERFORMANCE; FACILE SYNTHESIS; NABH4; SOLUTION; DEHYDROGENATION; EFFICIENT;

D O I：

10.1039/c8ta01093e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A facile and effective solvent-switched in situ confinement approach (SSISCA) has been developed to immobilize ultrafine and clean Pd NPs of similar to 1.75 nm into a nanoporous carbon support. The Pd NPs in situ confined within the carbon nanopores possess high catalytic activity and selectivity for hydrogen evolution from formic acid with a recordhigh TOF of 9110 h(-1) at 60 degrees C.

引用

页码：5544 / 5549

页数：6

共 63 条

[1] Surfactant-free Pd nanoparticles immobilized to a metal-organic framework with size- and location-dependent catalytic selectivity [J].

Aijaz, Arshad ;

Zhu, Qi-Long ;

Tsumori, Nobuko ;

Akita, Tomoki ;

Xu, Qiang .

CHEMICAL COMMUNICATIONS, 2015, 51 (13) :2577-2580

[2] Nanoceria supported palladium(0) nanoparticles: Superb catalyst in dehydrogenation of formic acid at room temperature [J].

Akbayrak, Serdar ;

Tonbul, Yalcin ;

Ozkar, Saim .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 206 :384-392

[3] Deactivation and reactivation of cobalt in hydrolysis of sodium borohydride [J].

Akdim, Ouardia ;

Demirci, Umit B. ;

Miele, Philippe .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (21) :13669-13675

[4]

[Anonymous], 2017, J AM CHEM SOC, DOI DOI 10.1021/JACS.7B03357

[5] Dehydrogenation of Formic Acid at Room Temperature: Boosting Palladium Nanoparticle Efficiency by Coupling with Pyridinic-Nitrogen-Doped Carbon [J].

Bi, Qing-Yuan ;

Lin, Jian-Dong ;

Liu, Yong-Mei ;

He, He-Yong ;

Huang, Fu-Qiang ;

Cao, Yong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (39) :11849-11853

[6] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions [J].

Bi, Qng-Yuan ;

Du, Xian-Long ;

Liu, Yong-Mei ;

Cao, Yong ;

He, He-Yong ;

Fan, Kang-Nian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) :8926-8933

[7] Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst [J].

Boddien, Albert ;

Mellmann, Doerthe ;

Gaertner, Felix ;

Jackstell, Ralf ;

Junge, Henrik ;

Dyson, Paul J. ;

Laurenczy, Gabor ;

Ludwig, Ralf ;

Beller, Matthias .

SCIENCE, 2011, 333 (6050) :1733-1736

[8] Continuous Hydrogen Generation from Formic Acid: Highly Active and Stable Ruthenium Catalysts [J].

Boddien, Albert ;

Loges, Bjoern ;

Junge, Henrik ;

Gaertner, Felix ;

Noyes, James R. ;

Beller, Matthias .

ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (14-15) :2517-2520

[9] Nano-architecture and material designs for water splitting photoelectrodes [J].

Chen, Hao Ming ;

Chen, Chih Kai ;

Liu, Ru-Shi ;

Zhang, Lei ;

Zhang, Jiujun ;

Wilkinson, David P. .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (17) :5654-5671

[10] Singlet Oxygen-Engaged Selective Photo-Oxidation over Pt Nanocrystals/Porphyrinic MOF: The Roles of Photothermal Effect and Pt Electronic State [J].

Chen, Yu-Zhen ;

Wang, Zhiyong U. ;

Wang, Hengwei ;

Lu, Junling ;

Yu, Shu-Hong ;

Jiang, Hai-Long .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) :2035-2044

← 1 2 3 4 5 6 7 →