Iron-promoted C-C bond formation in the total synthesis of natural products and drugs

被引：69

作者：

Legros, Julien ^{[1
,2
]}

Figadere, Bruno ^{[3
,4
]}

机构：

[1] Univ Rouen, COBRA UMR Normandie Univ 6014, INSA Rouen, F-76821 Mont St Aignan, France

[2] CNRS, F-76821 Mont St Aignan, France

[3] Univ Paris 11, BioCIS UMR Labex LERMIT 8076, CNRS, F-92296 Chatenay Malabry, France

[4] CNRS, F-92296 Chatenay Malabry, France

来源：

NATURAL PRODUCT REPORTS | 2015年 / 32卷 / 11期

关键词：

CROSS-COUPLING REACTIONS; CATALYZED CARBONYLATION-PEROXIDATION; ENANTIOSELECTIVE TOTAL-SYNTHESIS; GRIGNARD-REAGENTS; SCALABLE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; IRON(III) CHLORIDE; ATE COMPLEX; ROUTE; MILD;

D O I：

10.1039/c5np00059a

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Iron salts are inexpensive and almost innocuous; they are thus the promoters of choice, even in stoichiometric amounts, for the formation of carbon-carbon bonds in the backbone of complex molecules. This review encompasses the key role of iron complexes in the total synthesis of some natural products or pharmacologically important compounds.

引用

页码：1541 / 1555

页数：15

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