Synthesis and structure of a stable pentavalent-uranyl coordination polymer

被引：134

作者：

Natrajan, Louise

Burdet, Fabien

Pécaut, Jacques

Mazzanti, Marinella

机构：

[1] CEA, Lab Reconnaissance Ion, SCIB, UMR E 3,UJF,Dept Rech Fondamentale Mat Condensee, F-38054 Grenoble 09, France

[2] CEA, Lab Coordinat & Nanochim, SCIB, UMR E 3,UJF,Dept Rech Fondamentale Mat Condensee, F-38054 Grenoble 09, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 22期

关键词：

D O I：

10.1021/ja0609809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry. Copyright © 2006 American Chemical Society.

引用

页码：7152 / 7153

页数：2

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