2-methyldithiobenzoato-κS)(triphenylphosphine-κO) gold(I)

被引：6

作者：

Macalindong, JS ^{[1
]}

Fronczek, FR ^{[1
]}

Schuerman, JA ^{[1
]}

Selbin, J ^{[1
]}

Watkins, SF ^{[1
]}

机构：

[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806010725

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, o-CH3(C6H4)C(S)S-Au-P(C6H5)(3) or [Au(C8H7S2)(C18H15P)], consists of two quasi-linear gold complexes. The S-Au-P bond angles [173.83 (2), 175.03 (2)]degrees, S-Au bond lengths [2.3240 (6), 2.3329 (6) angstrom] and Au-P bond lengths [2.2568 (6), 2.2632 (6) angstrom] are consistent with previously reported values. The major difference in the two molecules is that the o-methylphenyl rings are twisted with respect to the dithiocarboxyl planes by 73.0 (3)degrees and 46.6 (3)degrees, as measured by S-C-C-C torsion angles.

引用

页码：M889 / M890

页数：2

共 10 条

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