Pyrolysis kinetics behavior of solid tire wastes available in Bangladesh

被引：48
|
作者：
Islam, M. Rofiqul [1 ]
Haniu, H. [2 ]
Fardoushi, J. [1 ]
机构：
[1] Rajshahi Univ Engn & Technol, Dept Mech Engn, Rajshahi 6204, Bangladesh
[2] Kitami Inst Technol, Dept Mech Engn, Kitami, Hokkaido 0908507, Japan
来源：
WASTE MANAGEMENT | 2009年 / 29卷 / 02期
基金：
日本学术振兴会;
关键词：
SCRAP AUTOMOTIVE TIRES; THERMAL-DEGRADATION; VACUUM PYROLYSIS; BATCH PYROLYSIS; LIMONENE ETHERS; PRODUCTS; RUBBER; OIL; COMPONENTS; REACTOR;
D O I：
10.1016/j.wasman.2008.04.009
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Pyrolysis kinetics of available bicycle/rickshaw, motorcycle and truck tire wastes in Bangladesh have been investigated thermogravimetrically in a nitrogen atmosphere at heating rates of 10 and 60 degrees C/min over a temperature range of 30-800 degrees C. The three tire wastes exhibited similar behaviors in that, when heating rate was increased, the initial reaction temperature decreased but the reaction range and reaction rate increased. The percentage of total weight loss was higher for truck tire waste and lower for bicycle/rickshaw tire waste. The pyrolysis of truck tire waste was found to be easier than that of bicycle/rickshaw and motorcycle tire wastes while it was comparatively more difficult for motorcycle tire waste. The overall rate equation for the three tire wastes has been modeled satisfactorily by one simplified equation from which the kinetic parameters of unreacted materials based on the Arrhenius form can be determined. The predicted rate equation compares fairly well with the measured TG and DTG data. DTA curves for all of the samples show that the degradation reactions are three main exotherms and one endotherm. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：668 / 677
页数：10
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