Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

被引：57

作者：

Rafter, Eoin ^{[1
]}

Gutmann, Torsten ^{[2
,3
]}

Loew, Florian ^{[4
]}

Buntkowsky, Gerd ^{[5
]}

Philippot, Karine ^{[2
,3
]}

Chaudret, Bruno ^{[6
]}

van Leeuwen, Piet W. N. M. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] CNRS, LCC, F-31077 Toulouse 4, France

[3] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France

[4] Tech Univ Darmstadt, Inst Phys Chem, D-64287 Darmstadt, Germany

[5] Tech Univ Darmstadt, Inst Condensed Matter Phys, D-64289 Darmstadt, Germany

[6] Univ Toulouse, INSA, UPS, CNRS,LPCNO, F-31077 Toulouse, France

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 03期

关键词：

SOLID-STATE NMR; RUTHENIUM NANOPARTICLES; H-2; NMR; HYDROFORMYLATION; COMPLEXES; CATALYSTS; HYDROGENATION; ACTIVATION; PRELIGANDS;

D O I：

10.1039/c2cy20683h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1-2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h(-1).

引用

收藏

页码：595 / 599

页数：5

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