Cobalt assisted cleavage of S-S bonds and a base-free synthesis of mercapturic acids

被引:59
作者
Chowdhury, S [1 ]
Roy, S [1 ]
机构
[1] INDIAN INST CHEM TECHNOL,METALLOORGAN LAB,DIV PC&1,HYDERABAD 500007,ANDHRA PRADESH,INDIA
关键词
D O I
10.1016/S0040-4039(97)00268-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Base free transformation of PhSSPh to sulfides, PhSR (R= alkyl, benzyl, allyl, acyl) and N-acetyl-L-cystine to mercapturic rids [AcNHCH(COOH)CH,SR R= alkyl, benzyl allyl acyl] have been achieved using Zn / cat. CoCI2/ organic halide in MeCN at room temperature. (C) 1997 Elsevier Science Ltd.
引用
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页码:2149 / 2152
页数:4
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