Bis(1,10-phenanthroline-κ2N, N′)(sulfato-κ2O,O′)cobalt(II) 1,2-ethanediol solvate

被引：15
|
作者：
Zhong, KL [1 ]
Zhu, YM [1 ]
Lu, WJ [1 ]
机构：
[1] Wuyi Univ, Dept Chem & Environm Engn, Jiangmen, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806002315
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(SO4)(C12H8N2)(2)]center dot C2H6O2, a twofold rotation axis passes through the Co and S atoms, and through the mid-point of the solvent C-C bond. The coordination environment of the Co-II centre is a distorted CoN4O2 octahedron, with four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from a bidentate sulfate ligand. The two chelating N2C2 groups are oriented at 70.16 (6)degrees to each other. Intermolecular O-H center dot center dot center dot O hydrogen bonds help to stabilize the structure.
引用
收藏
页码：M631 / M633
页数：3
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