Synthesis and characterization of novel polymers bearing fluorescein units: thermal and optical properties

被引：13
作者：
Esquivel-Guzman, Jair A. [1 ]
Zaragoza-Galan, Gerardo [1 ]
Ortiz-Palacios, Jesus [1 ]
Rivera, Ernesto [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Invest & Mat, Mexico City 04510, DF, Mexico
来源：
DESIGNED MONOMERS AND POLYMERS | 2012年 / 15卷 / 06期
关键词：
polymer; fluorescein; poly(ethylene glycol); optical properties; MODIFIED RHODAMINE 6G; ORGANIC LASER-DYES; METHACRYLATE MIXTURES; SPECTRAL PROPERTIES; PYRENE; COPOLYMERS; BEHAVIOR; DERIVATIVES; MECHANISMS; DESIGN;
D O I：
10.1080/1385772X.2012.688339
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this work, we report the synthesis and characterization of four novel series of copolymers bearing fluorescein moieties. Two monomers: fluorescein methacrylate and dimethacrylate were prepared and were copolymerized in the presence of four different acrylic monomers bearing oligo(ethylene glycol) segments: ethylene glycol phenyl ether acrylate, ethylene glycol phenyl ether methacrylate, poly(ethylene glycol) methyl ether acrylate (Mn = 475 g/mol), and poly(ethylene glycol) methyl ether methacrylate (Mn = 480 g/mol). The obtained copolymers were fully characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Proton Nuclear Magnetic Resonance (H-1 NMR) spectroscopy. Their thermal properties were determined by thermogravimetric analysis and differential scanning calorimetry, and their optical properties were studied by absorption and fluorescence spectroscopy in solution and in solid state.
引用
收藏
页码：561 / 574
页数：14
相关论文
共 41 条
  • [1] Thermal degradation of light-cured dimethacrylate resins - Part I. Isoconversional kinetic analysis
    Achilias, Dimitris S.
    Karabela, Maria M.
    Sideridou, Irini D.
    [J]. THERMOCHIMICA ACTA, 2008, 472 (1-2) : 74 - 83
  • [2] Design of fluorescent materials for chemical sensing
    Basabe-Desmonts, Lourdes
    Reinhoudt, David N.
    Crego-Calama, Mercedes
    [J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (06) : 993 - 1017
  • [3] Elastomeric azo-polyurethanes containing fluorescent pyrene and their photo activity
    Buruiana, Emil C.
    Buruiana, Tinca
    Zamfir, Mirela
    Pohoata, Valentin
    Donescu, Dan
    [J]. DESIGNED MONOMERS AND POLYMERS, 2007, 10 (04) : 347 - 360
  • [4] The influence of labelling mechanisms on the fluorescence behaviour of polymers bearing fluorescein labels
    Carvell, M
    Robb, ID
    Small, PW
    [J]. POLYMER, 1998, 39 (02) : 393 - 398
  • [5] Proton-transfer lasers based on solid copolymers of modified 2-(2′-hydroxyphenyl)benzimidazoles with methacrylate monomers
    Costela, A
    Garcia-Moreno, I
    Mallavia, R
    Amat-Guerri, F
    Barroso, J
    Sastre, R
    [J]. OPTICS COMMUNICATIONS, 1998, 152 (1-3) : 89 - 95
  • [6] Characterization of interpenetrating polymer-like network based on polyethylene/poly(styrene-co-butylmethacrylate) (PE/P(S-co-BMA)) by non-radiative energy transfer
    Danko, M
    Hrdlovic, P
    Borsig, E
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 154 (2-3) : 279 - 288
  • [7] Spectral characteristics of free and linked pyrene-type chromophores in solution, polymer matrices, and interpenetrating networks
    Danko, M
    Hrdlovic, P
    Borsig, E
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2001, 38 (5-6): : 467 - 486
  • [8] Spectroscopic properties of Na-fluorescein in polyacrylic acid films
    Deshpande, AV
    Namdas, EB
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 110 (02) : 177 - 182
  • [9] Du H, 1998, PHOTOCHEM PHOTOBIOL, V68, P141, DOI 10.1562/0031-8655(1998)068<0141:PACADA>2.3.CO
  • [10] 2
12345