Reactions of dichloro-substituted iron(ii) clathrochelate with 1,4-dioxane radical derivatives: synthesis, structure, and spectral characteristics of the dioxane ring opening product in the ribbed fragment of the macrobicyclic ligand

被引：4

作者：

Vershinin, M. A. ^{[1
]}

Burdukov, A. B. ^{[1
]}

Starikova, Z. A. ^{[2
]}

Novikov, V. V. ^{[2
]}

Voloshin, Ya. Z. ^{[2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

clathrochelates; reactions of coordinated ligands; free-radical reactions; REACTIVITY; FRAMEWORK;

D O I：

10.1007/s11172-011-0386-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A free-radical substitution for the chlorine atoms with the 1,4-dioxan-2-yl fragment in the tris-dichloro-substituted dioximate iron(II) clathrochelate is accompanied by the oxidative dioxane ring opening as a side process. The compound obtained was characterized by elemental analysis data, 1D and 2D H-1 and C-13{H-1} NMR spectroscopy (in solution), MALDI TOF mass spectrometry, as well as by single-crystal X-ray diffraction.

引用

页码：2510 / 2517

页数：8

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