A Thermally and Hydrolytically Stable Microporous Framework Exhibiting Single-Chain Magnetism: Structure and Properties of [Co2(H0.67bdt)3]•20H2O

被引：161

作者：

Ouellette, Wayne ^{[2
]}

Prosvirin, Andrey V. ^{[1
]}

Whitenack, Kelly ^{[2
]}

Dunbar, Kim R. ^{[1
]}

Zubieta, Jon ^{[2
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 12期

基金：

美国国家科学基金会;

关键词：

cobalt; hydrothermal synthesis; magnetic properties; organic-inorganic hybrid composites; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; COORDINATION CHEMISTRY; HYDROTHERMAL SYNTHESIS; CONVERSION; SOLIDS; SYSTEM;

D O I：

10.1002/anie.200804805

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fixing a hole: Hydrothermal chemistry has been exploited in the preparation of a 3D framework material exhibiting 48 % accessible void volume and 1.5 % hydrogen uptake by weight at 120 kPa (see picture). The title compound also exhibits single-chain magnetic behavior and reversible changes in magnetic properties upon solvation and desolvation. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2140 / 2143

页数：4

共 47 条

[1] Cobalt(II) complexes of pyridazine or triazole containing ligands: spin-state control [J].