Syntheses and Structures of Two New Borates: [NH3(CH2)3N(CH2)4N(CH2)3NH3][B5O6(OH)4]2 and [NH2(CH2)4N(CH2)2NH3][B7O10(OH)3]

被引：4

作者：

Wu, Lian-Zhi ^{[1
]}

Cheng, Lin ^{[1
]}

Yang, Guo-Yu ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2013年 / 24卷 / 03期

关键词：

Hydrothermal synthesis; Borate; Amine; Cluster; CRYSTAL-STRUCTURE; 1ST EXAMPLES; CHEMISTRY;

D O I：

10.1007/s10876-013-0577-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new borates, [NH3(CH2)(3)N(CH2)(4)N(CH2)(3)NH3][B5O6(OH)(4)](2) (1) and [NH2(CH2)(4)N(CH2)(2)NH3][B7O10(OH)(3)] (2), have been made under hydrothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P2(1)/c, a = 9.504(3) , b = 14.305(4) , c = 10.513(3) , beta = 90.313(5)A degrees, Z = 2. Crystal data for 2: triclinic, P (1) over bar, a = 9.196(3) , b = 9.722(3) , c = 11.361(3) , alpha = 71.232(11)A degrees, beta = 71.603(10)A degrees, gamma = 72.354(12)A degrees, Z = 2. The protonated organic amines are filled in the free space of the hydrogen- bonded network and interact with the inorganic framework by extensive hydrogen bonds.

引用

页码：811 / 820

页数：10

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