Hydrogenation of Aliphatic and Aromatic Nitriles Using a Defined Ruthenium PNP Pincer Catalyst

被引：53
作者：
Neumann, Jacob [1 ]
Bornschein, Christoph [1 ]
Jiao, Haijun [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构：
[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 27期
关键词：
Ruthenium; Hydrogenation; Nitrile; Amines; CARBOXYLIC-ACID ESTERS; PRIMARY AMINES; SELECTIVE HYDROGENATION; REDUCTIVE AMINATION; HYDROAMINATION; MILD; DEHYDROGENATION; BENZONITRILE; COMPLEXES; ALDEHYDES;
D O I：
10.1002/ejoc.201501007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective catalytic reductions of nitriles are presented using the commercially available Ru-Macho-BH complex. A variety of aliphatic, aromatic and (hetero)cyclic nitriles including industrially important adipodinitrile are hydrogenated to the corresponding primary amines. Modelling suggests the reaction follows an outer sphere hydrogenation mechanism.
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收藏
页码：5944 / 5948
页数：5
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