Solid state coordination chemistry of molybdenum oxides: Construction of bimetallic organic-inorganic hybrid materials from Keggin clusters and copper-imine building blocks

被引：9

作者：

Jones, Stephanie ^{[1
]}

Aldous, Amanda ^{[1
]}

Burkholder, Eric ^{[1
]}

Zubieta, Jon ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

POLYHEDRON | 2013年 / 52卷

关键词：

Bimetallic oxides; Keggin cluster building units; Hydrothermal synthesis; Copper-organonitrogen ligand chains and networks; TRANSITION-METAL-COMPLEXES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; ANTISYMMETRIC EXCHANGE; POLYOXOMOLYBDATE CLUSTERS; ORGANONITROGEN COMPLEXES; OCTAMOLYBDATE CLUSTERS; TRIANGULAR TRINUCLEAR;

D O I：

10.1016/j.poly.2012.08.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unexpected hydrolysis of organophosphonic acid ligands under hydrothermal reaction conditions yielded four bimetallic oxide materials incorporating Keggin type polyanions. The one-dimensional [Cu4O(Htpyprz)(tpyPrz)(2)Cl-4] [Mo12PO40] (1), [Cu-6(4-pyrtet)(2)(4-Hpyrtet)(4)][(MoMo11PO40)-Mo-V-P-V-P-I]center dot 2.5H(2)O (2.2.5H(2)P), and [Cu-3(OH)(4-pyrtet)(2)(4-Hpyrtet)(2)(H2O)(2)] [Mo12PO40]center dot 10.5H(2)O (3.10.5H(2)O) and the two-dimensional [Cu-3(OH)(4-pyrtet)(3)(4-H(2)pyrtet)(H2O)] [Mo12PO40]center dot 7.5H(2)O (4.7.5H(2)O) (tpyprz = tetra-4-pyridyl pyrazine; 4-Hpyrtet = 4-pyridyltetrazole) demonstrate the variety of ways in which Keggin clusters may influence the configuration of the secondary metal-ligand substructure. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：582 / 590

页数：9

共 153 条

[61] Polyoxomolybdate clusters and tetranuclear copper-organonitrogen complexes as building blocks for the design of three-dimensional oxide frameworks [J].