Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2

被引:1
|
作者
Wang, Hong [1 ]
Lu, Bin [2 ]
Zhao, Jingxiang [2 ]
Cai, Qinghai [2 ]
机构
[1] Harbin Univ Sci & Technol, Sch Chem & Environm Engn, Harbin 150080, Peoples R China
[2] Harbin Normal Univ, Sch Chem & Chem Engn, Harbin 150025, Peoples R China
关键词
Ionothermal technique; ionic liquid; single crystal; crystal structure; IONIC LIQUIDS; CRYSTAL-STRUCTURE; COMPLEXES;
D O I
10.1007/s12039-015-0894-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ionothermal synthesis and spectroscopic, thermal and structural characterization of two new compounds [Cu(C4H6N2)(4)]Br-2 (1) and [Ni(C4H6N2)(4)]Br-2 (2) [(C4H6N2)= N-methylimidazole] are reported. In both 1 and 2, the central metal Cu (or Ni) ion adopts a square planar geometry and is bonded to the N-atoms of four terminal N-methylimidazole ligands.
引用
收藏
页码:1261 / 1265
页数:5
相关论文
共 50 条
  • [31] Generation of a high symmetry 2D-polybromide network in the structure of {[(o-SCH3C6H4)3PBr][Br]•0.5(μ-Br2)3}n. The templating effect of the C3 symmetric [(o-SCH3C6H4)3PBr]+ cation
    Alhanash, Fatma B.
    Barnes, Nicholas A.
    Godfrey, Stephen M.
    Khan, Rana Z.
    Pritchard, Robin G.
    POLYHEDRON, 2013, 65 : 102 - 109
  • [32] Synthesis, Structure and Characterization of a New Complex: [Mn(C6H12N4)2(H2O)4][Mn(H2O)6][SO4]2•t6H2O
    Li Deng-Peng
    Xu Zhi-Huang
    Ye Li-Wang
    Cao Teng-Fei
    Zhuang Xin-Xin
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40 (09) : 1169 - 1176
  • [33] A Reactive Intermediate, [Ni5(C6H4N3)6(CO)4], in the Formation of Nonameric Clusters of Nickel, [Ni9(C6H4N3)12(CO)6] and [Ni9(C6H4N3)12(CO)6].2(C3H7NO)
    Mistry, Subhradeep
    Natarajan, Srinivasan
    JOURNAL OF CHEMICAL SCIENCES, 2014, 126 (05) : 1477 - 1491
  • [34] Synthesis, crystal structure and solubility of C6H14N4O2,C4H4O4,2H2O
    Mallik, T
    Kar, T
    Bocelli, G
    Musatti, A
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2005, 6 (05) : 508 - 512
  • [35] Synthesis, spectroscopic, structural and thermal characterizations of [(C7H6NO4)2TeBr6•4H2O]
    Smaoui, S.
    Kabadou, A.
    Van Der Lee, A.
    Ben Salah, A.
    Abdelmouleh, M.
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2018, 22 (02) : 155 - 164
  • [36] Speciation and transformation in the synthesis of Cu4(im)4(C4O3H6)2(NO2)4(H2O)4 and [(phen)Cu(C2O4)(H2O)]•H2O
    Gong, Yun
    Li, Hui
    Li, Yang Guang
    Wang, Yong Hui
    Tang, Wang
    Hu, Chang Wen
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (01) : 61 - 71
  • [37] Hydrothermal synthesis and crystal structure of a new phosphonate:: {[Cu(1,10-phen)]2(H2O3PCH2C6H4C6H4CH2PO3H)2- (HO3PCH2C6H4C6H4CH2PO3H)}n
    Fu, RB
    Wu, XT
    Hu, SM
    Wang, LS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (10) : 1107 - 1110
  • [38] Architecture of framework copper(I) halide π-complexes with N-allyl-N,N,N′,N′-tetramethyl-ethylenediaminium and N,N′-diallyl-N,N,N′,N′-tetramethylethylenediaminium: Synthesis and crystal structure of [{C2H4N2(H+)×(CH3)4(C3H5)} Cu4Cl6] and [{C2H4N2(CH3)4(C3H5)2}0.5Cu2Cl1.67Br1.33]
    M. M. Monchak
    E. A. Goreshnik
    M. G. Mys’kiv
    Journal of Structural Chemistry, 2012, 53 : 119 - 124
  • [39] Bromine-rich Zinc Bromides: Zn6Br12(18-crown-6)2x(Br2)5, Zn4Br8(18-crown-6)2x(Br2)3, and Zn6Br12(18-crown-6)2x(Br2)2
    Hausmann, David
    Feldmann, Claus
    INORGANIC CHEMISTRY, 2016, 55 (12) : 6141 - 6147
  • [40] Br2-free method for XBr3 (X = Cs, C8H20N, C16H36N) synthesis: Br2 solid storage and separation from aqueous solution
    Lin, Yang-Peng
    Huang, Xiao-Ying
    Du, Ke-Zhao
    MATERIALS CHEMISTRY AND PHYSICS, 2022, 280