Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2

被引：1
|
作者：
Wang, Hong [1 ]
Lu, Bin [2 ]
Zhao, Jingxiang [2 ]
Cai, Qinghai [2 ]
机构：
[1] Harbin Univ Sci & Technol, Sch Chem & Environm Engn, Harbin 150080, Peoples R China
[2] Harbin Normal Univ, Sch Chem & Chem Engn, Harbin 150025, Peoples R China
来源：
JOURNAL OF CHEMICAL SCIENCES | 2015年 / 127卷 / 07期
关键词：
Ionothermal technique; ionic liquid; single crystal; crystal structure; IONIC LIQUIDS; CRYSTAL-STRUCTURE; COMPLEXES;
D O I：
10.1007/s12039-015-0894-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ionothermal synthesis and spectroscopic, thermal and structural characterization of two new compounds [Cu(C4H6N2)(4)]Br-2 (1) and [Ni(C4H6N2)(4)]Br-2 (2) [(C4H6N2)= N-methylimidazole] are reported. In both 1 and 2, the central metal Cu (or Ni) ion adopts a square planar geometry and is bonded to the N-atoms of four terminal N-methylimidazole ligands.
引用
收藏
页码：1261 / 1265
页数：5
相关论文
共 50 条
  • [21] Synthesis and structural characterization of a novel coordination polymer [Cd(C4H2O4)(C3H4N2)3]n•2nH2O
    Yue, L
    Zhou, QX
    Wang, YJ
    Zhao, XQ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (03) : 287 - 290
  • [22] Synthesis and crystal structure of the binuclear complex [Pr2(C10H8N2O4)2(C10H9N2O4)2(H2O)4]•3H2O•C6H6
    Wu, WT
    Chen, FY
    He, SY
    Hu, HM
    Yang, ML
    Wang, YY
    CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (05) : 711 - 713
  • [23] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [24] Synthesis and Crystal Structure of Dinuclear Copper Complex [Cu(CH2O（C6H4）N=C（C6H4）O)（Py）]2
    NIU De-Zhong① MU Lai-Long LU Zai-Sheng WANG Yu-Cheng (Department of Chemistry
    结构化学, 2002, (01) : 55 - 59
  • [25] Synthesis and crystal structure of dinuclear copper complex [Cu(CH2O(C6H4)N=C(C6H4)O)(Py)]2
    Niu, DZ
    Mu, LL
    Lu, ZS
    Wang, YC
    Chen, JT
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (01) : 55 - 59
  • [26] NEW N-SUBSTITUTED POLYAMINES. SYNTHESIS, CHARACTERIZATION AND CRYSTAL AND MOLECULAR STRUCTURE OF 2-[{C6H4(CO)2NCH2CH2}2NCH2]C6H4Br
    Coros, Maria
    Domide, Dan
    Vlassa, Mircea
    Soran, Albert
    Silvestru, Cristian
    REVUE ROUMAINE DE CHIMIE, 2010, 55 (11-12) : 803 - +
  • [27] Synthesis, Crystal Structure and Properties of a Coordination Compound: Ni(C6H12N4)2SO4•4H2O
    Gao Sheng-Min
    Xu Zhi-Huang
    Ye Li-Wang
    Su Gen-Bo
    Zhuang Xin-Xin
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (11) : 1682 - 1688
  • [28] Synthesis and Crystal Structure of [Y(C6H4NO2)2(H2O)4]n•nCl
    Chen, Wen-Tong
    Luo, Zhi-Gang
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (07) : 4077 - 4079
  • [29] Synthesis,Crystal Structure and Properties of a Coordination Compound:Ni(C6H12N4)2SO4·4H2O
    高晟民
    许智煌
    叶李旺
    苏根博
    庄欣欣
    结构化学, 2015, 34 (11) : 1682 - 1688
  • [30] Architecture of framework copper(I) halide π-complexes with N-allyl-N,N,N',N'-tetramethyl-ethylenediaminium and N,N'-diallyl-N,N,N',N'-tetramethylethylenediaminium: Synthesis and crystal structure of [{C2H4N2(H+)x(CH3)4(C3H5)} Cu4Cl6] and [{C2H4N2(CH3)4(C3H5)2}0.5Cu2Cl1.67Br1.33]
    Monchak, M. M.
    Goreshnik, E. A.
    Mys'kiv, M. G.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (01) : 119 - 124
12345