Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2

被引:1
|
作者
Wang, Hong [1 ]
Lu, Bin [2 ]
Zhao, Jingxiang [2 ]
Cai, Qinghai [2 ]
机构
[1] Harbin Univ Sci & Technol, Sch Chem & Environm Engn, Harbin 150080, Peoples R China
[2] Harbin Normal Univ, Sch Chem & Chem Engn, Harbin 150025, Peoples R China
关键词
Ionothermal technique; ionic liquid; single crystal; crystal structure; IONIC LIQUIDS; CRYSTAL-STRUCTURE; COMPLEXES;
D O I
10.1007/s12039-015-0894-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ionothermal synthesis and spectroscopic, thermal and structural characterization of two new compounds [Cu(C4H6N2)(4)]Br-2 (1) and [Ni(C4H6N2)(4)]Br-2 (2) [(C4H6N2)= N-methylimidazole] are reported. In both 1 and 2, the central metal Cu (or Ni) ion adopts a square planar geometry and is bonded to the N-atoms of four terminal N-methylimidazole ligands.
引用
收藏
页码:1261 / 1265
页数:5
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