The 4,4′-bipyridine Bi3+ coordination polymer involving simultaneous of two different 1D chains in one system, [4,4′-bipyH]nn+[Bi(4,4′-bipy)Br4]nn-, thermal and structural studies

被引:44
作者
Morsali, A [1 ]
机构
[1] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran, Iran
关键词
bismuth(III); crystal structure; 4,4 '-bipyridine; hydrogen bond; coordination polymer;
D O I
10.1016/j.solidstatesciences.2005.10.004
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The single-crystal X-ray data of a 4,4'-bipyridine bismuth(Ill) complex shows that the compound contain two anionic and cationic ID chains, [4,4'-bipyH](n)(n+)[Bi(4,4'-bipy)Br-4](n)(n-). Two one-dimensional systems grow into a three-dimensional network by packing, via extensively hydrogen-bond network. (c) 2005 Elsevier SAS. All rights reserved.
引用
收藏
页码:82 / 85
页数:4
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