Effect of conducting polymer layer on microwave absorption properties of BaFe12O19-TiO2 composite

被引:20
作者
Akman, O. [1 ,2 ]
Durmus, Z. [3 ]
Kavas, H. [4 ]
Aktas, B. [1 ]
Kurtan, U. [3 ]
Baykal, A. [3 ]
Sozeri, H. [5 ]
机构
[1] Gebze Inst Technol GYTE, Dept Phys, TR-41400 Gebze, Turkey
[2] Sakarya Univ, Dept Phys, TR-54100 Sakarya, Turkey
[3] Fatih Univ, Dept Chem, TR-34500 B Cekmece Istanbul, Turkey
[4] Istanbul Medeniyet Univ, Dept Engn Phys, TR-34720 Istanbul, Turkey
[5] Natl Metrol Inst, TUBITAK UME, TR-41470 Gebze, Turkey
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2013年 / 210卷 / 02期
关键词
conducting polymers; hexaferrite; microwave absorption; nanocomposites; TiO2; ZR; PERMITTIVITY; ENHANCEMENT; PARTICLES; FE3O4;
D O I
10.1002/pssa.201228498
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ba-hexaferrite (BaM) particles, synthesized by a sol-gel route, have been mixed with TiO2 powders with different mass ratios. The obtained BaM-TiO2 composites have been coated with a conducting polymer layer of polypyrrole (PPy). Structural, magnetic and microwave absorption properties of the PPy-coated and uncoated BaM-TiO2 composites have been investigated by X-ray diffractometry (XRD), scanning/tunneling electron microscopy, magnetization, and near-field microwave measurements in the frequency range of 8-18 GHz. The dielectric loss of the PPy-coated composites appeared to be higher compared to the uncoated samples in the whole frequency range. A single matching frequency was observed for each of the coated and uncoated samples in the frequency range between 16 and 18 GHz. Despite their relatively low absorption properties of uncoated composites (similar to -30 dB), PPy-coated ones have wide absorption bandwidths at -20 dB. The main absorption mechanism in all samples, coated and uncoated, is dielectric loss. (C) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:395 / 402
页数:8
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