LiCrTiO4: A High-Performance Insertion Anode for Lithium-Ion Batteries

被引:49
作者
Aravindan, Vanchiappan [1 ]
Ling, Wong Chui [1 ]
Madhavi, Srinivasan [1 ,2 ,3 ]
机构
[1] Nanyang Technol Univ, Energy Res Inst ERI N, Singapore 637553, Singapore
[2] Nanyang Technol Univ, TUM CREATE Ctr Electromobil, Singapore 639798, Singapore
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
新加坡国家研究基金会;
关键词
electrochemistry; full cells; insertion anode; lithium-ion batteries; lithium chromium titanate; HYBRID SUPERCAPACITORS; ELECTROLYTE; CELLS;
D O I
10.1002/cphc.201200398
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bring on the power: A high-performance insertion-type LiCrTiO4 anode is synthesized by solid-state-reaction methods. Reversible insertion of almost one mole of lithium is achieved in the half-cell configuration. The picture shows a TEM image of LiCrTiO4 with superimposed cyclic voltammetric traces of a LiMn2O4/LiCrTiO4 cell. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3263 / 3266
页数:4
相关论文
共 17 条
[1]   Carbon coated nano-LiTi2(PO4)3 electrodes for non-aqueous hybrid supercapacitors [J].
Aravindan, V. ;
Chuiling, W. ;
Reddy, M. V. ;
Rao, G. V. Subba ;
Chowdari, B. V. R. ;
Madhavi, S. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (16) :5808-5814
[2]   Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode [J].
Aravindan, V. ;
Reddy, M. V. ;
Madhavi, S. ;
Mhaisalkar, S. G. ;
Rao, G. V. Subba ;
Chowdari, B. V. R. .
JOURNAL OF POWER SOURCES, 2011, 196 (20) :8850-8854
[3]   Influence of carbon towards improved lithium storage properties of Li2MnSiO4 cathodes [J].
Aravindan, V. ;
Karthikeyan, K. ;
Kang, K. S. ;
Yoon, W. S. ;
Kim, W. S. ;
Lee, Y. S. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (08) :2470-2475
[4]   Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries [J].
Aravindan, Vanchiappan ;
Gnanaraj, Joe ;
Madhavi, Srinivasan ;
Liu, Hua-Kun .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (51) :14326-14346
[5]   TiO2(B) nanowires as an improved anode material for lithium-ion batteries containing LiFePO4 or LiNi0.5Mn1.5O4 cathodes and a polymer electrolyte [J].
Armstrong, Graham ;
Armstrong, A. Robert ;
Bruce, Peter G. ;
Reale, Priscilla ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2006, 18 (19) :2597-+
[6]   Facile synthesis of nano-Li4 Ti5O12 for high-rate Li-ion battery anodes [J].
Jin, Yun-Ho ;
Min, Kyung-Mi ;
Shim, Hyun-Woo ;
Seo, Seung-Deok ;
Hwang, In-Sung ;
Park, Kyung-Soo ;
Kim, Dong-Wan .
NANOSCALE RESEARCH LETTERS, 2012, 7 :1-6
[7]  
Kumar T. Prem, 2009, Journal of the Indian Institute of Science, V89, P393
[8]   Comparative study of Li[CrTi]O4, Li[Li1/3Ti5/3]O4and Li1/2Fe1/2[Li1/2Fe1/2Ti]O4 in non-aqueous lithium cells [J].
Mukai, K ;
Ariyoshi, K ;
Ohzuku, T .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :213-216
[9]   High-rate nano-crystalline Li4Ti5O12 attached on carbon nano-fibers for hybrid supercapacitors [J].
Naoi, Katsuhiko ;
Ishimoto, Shuichi ;
Isobe, Yusaku ;
Aoyagi, Shintaro .
JOURNAL OF POWER SOURCES, 2010, 195 (18) :6250-6254
[10]   The development of lithium ion secondary batteries [J].
Nishi, Y .
CHEMICAL RECORD, 2001, 1 (05) :406-413