B13+: A Photodriven Molecular Wankel Engine

被引：67
|
作者：
Zhang, Jin [1 ]
Sergeeva, Alina P. [2 ]
Sparta, Manuel [1 ]
Alexandrova, Anastassia N. [1 ]
机构：
[1] Univ Calif Los Angeles, Dept Chem & Biochem, 607 Charles E Young Dr E,Box 951569, Los Angeles, CA 90095 USA
[2] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 34期
关键词：
ab initio calculations; Born-Oppenheimer molecular dynamics; boron; molecular motors; nanomachines; CLUSTER IONS; AB-INITIO; MOTOR; B-13(+); STABILITY; B-19(-); DRIVEN;
D O I：
10.1002/anie.201202674
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Revved-up rotary: A molecular Wankel motor, the dual-ring structure B13+, is driven by circularly-polarized infrared electromagnetic radiation. Calculations show that this illumination leads to a guided unidirectional rotation of the outer ring, which is achieved with rotational frequency of the order of 300?GHz.
引用
收藏
页码：8512 / 8515
页数：4
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