Oxidative Aminoarylselenation of Maleimides via Copper-Catalyzed Four-Component Cross-Coupling

被引：37

作者：

Gao, Xue ^{[1
]}

Tang, Liyang ^{[1
]}

Huang, Lehao ^{[1
]}

Huang, Zu-Sheng ^{[1
]}

Ma, Yunfei ^{[1
]}

Wu, Ge ^{[1
,2
]}

机构：

[1] Wenzhou Med Univ, Sch Pharmaceut Sci, Wenzhou 325035, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 03期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; ELEMENTAL SULFUR; ARYL IODIDES; HYDROSELENATION; ALKYNES; BOND; SE; FUNCTIONALIZATION; SULFIDES; SELENIUM;

D O I：

10.1021/acs.orglett.8b03980

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of copper-catalyzed four-component coupling reaction of aryl iodides, Se powder, secondary amines, and maleimides is developed. This reaction provides an efficient and concise route to access amino-arylselenated maleimides via double C-Se bonds and C-N bond formation. The appealing features of this transformation are the use of Se powder as a selenating reagent, a green catalytic system, a wide range of substrate scope, and late-stage selenation of bioactive compounds.

引用

页码：745 / 748

页数：4

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