Oxidative Aminoarylselenation of Maleimides via Copper-Catalyzed Four-Component Cross-Coupling

被引:36
作者
Gao, Xue [1 ]
Tang, Liyang [1 ]
Huang, Lehao [1 ]
Huang, Zu-Sheng [1 ]
Ma, Yunfei [1 ]
Wu, Ge [1 ,2 ]
机构
[1] Wenzhou Med Univ, Sch Pharmaceut Sci, Wenzhou 325035, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
ONE-POT SYNTHESIS; ELEMENTAL SULFUR; ARYL IODIDES; HYDROSELENATION; ALKYNES; BOND; SE; FUNCTIONALIZATION; SULFIDES; SELENIUM;
D O I
10.1021/acs.orglett.8b03980
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first example of copper-catalyzed four-component coupling reaction of aryl iodides, Se powder, secondary amines, and maleimides is developed. This reaction provides an efficient and concise route to access amino-arylselenated maleimides via double C-Se bonds and C-N bond formation. The appealing features of this transformation are the use of Se powder as a selenating reagent, a green catalytic system, a wide range of substrate scope, and late-stage selenation of bioactive compounds.
引用
收藏
页码:745 / 748
页数:4
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